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8. For each of the following compounds, draw the most stable conformation and indicate the number of gauche and 1,3-diaxial interactions present. For molecules that can exist in another chair conformation, estimate the energy difference between the two forms (gauche interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol). H3C H3C H3C CH3 "CH3 a b C CH3 CH3 CH3 H3C H3C d e

8. For each of the following compounds, draw the most stable conformation and indicate the number of gauche and 1,3-diaxial interactions present. For molecules that can exist in another chair conformation, estimate the energy difference between the two forms (gauche interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol). H3C H3C H3C CH3 "CH3 a b C CH3 CH3 CH3 H3C H3C d e

Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter7: Cycloalkanes
Section: Chapter Questions
Problem 12CTQ: Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth...
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8. For each of the following compounds, draw the most stable conformation and indicate the number of gauche and 1,3-diaxial interactions present. For molecules that can exist in another chair conformation, estimate the energy difference between the two forms (gauche interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol). H3C H3C H3C CH3 "CH3 a b C CH3 CH3 CH3 H3C H3C d e
Transcribed Image Text:8. For each of the following compounds, draw the most stable conformation and indicate the number of gauche and 1,3-diaxial interactions present. For molecules that can exist in another chair conformation, estimate the energy difference between the two forms (gauche interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol). H3C H3C H3C CH3 "CH3 a b C CH3 CH3 CH3 H3C H3C d e
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