8. For each of the following compounds, draw the most stable conformation and indicate the number of gauche and 1,3-diaxial interactions present. For molecules that can exist in another chair conformation, estimate the energy difference between the two forms (gauche interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol). H3C H3C H3C CH3 "CH3 a b C CH3 CH3 CH3 H3C H3C d e
8. For each of the following compounds, draw the most stable conformation and indicate the number of gauche and 1,3-diaxial interactions present. For molecules that can exist in another chair conformation, estimate the energy difference between the two forms (gauche interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol). H3C H3C H3C CH3 "CH3 a b C CH3 CH3 CH3 H3C H3C d e
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.35P: Consider 1-bromo-2-methylpropane and draw the following. (a) The staggered conformation(s) of lowest...
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Transcribed Image Text:8. For each of the following compounds, draw the most stable conformation and indicate the
number of gauche and 1,3-diaxial interactions present. For molecules that can exist in
another chair conformation, estimate the energy difference between the two forms (gauche
interactions = 0.9 kcal/mol; 1,3-diaxial Me-Me interactions = 3.7 kcal/mol).
H3C
H3C
H3C
CH3
"CH3
a
b
C
CH3
CH3
CH3
H3C
H3C
d
e
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