8-7. Suppose a 185 gram sample of hydrogen reacts with an excess of nitrogen dioxide as follows: 2 NO2 (g) + 7 H2 (g) → 2 NH3 (g) + 4 H2O(g) Both products are collected together (separate from any remaining reactants) in a 325 liter vessel at 512 K. a. How many moles of ammonia gas are produced? b. How many moles of water vapor are produced? c. What is the total pressure in the product collection vessel after the reaction is complete?
Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
8-7. Suppose a 185 gram sample of hydrogen reacts with an excess of nitrogen dioxide as follows:
2 NO2 (g) + 7 H2 (g) → 2 NH3 (g) + 4 H2O(g)
Both products are collected together (separate from any remaining reactants) in a 325 liter vessel at 512 K.
a. How many moles of ammonia gas are produced?
b. How many moles of water vapor are produced?
c. What is the total pressure in the product collection vessel after the reaction is complete?
8-8. Suppose 93.4 grams of aluminum sulfide are added to 5.00 liters of a 0.844 M hydrochloric acid
solution and the following reaction takes place:
6 HCl (aq) + Al2S3 (s) → 3 H2S (g) + 2 AlCl3 (aq)
a. Which reactant is the limiting reactant?
b. Briefly explain how you know which reactant is limiting. Be specific. Use complete sentences.
c. What volume of hydrogen sulfide gas is collected at STP?
d. How many grams of aluminum sulfide will be left over at the end?
e. What is the final molarity of HCl?
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