7a. All of the following IR spectra are from arenes, but which one is likely from a monosubstituted alkyl benzene? (Circle the letter A, B, C, D; and see below.) Assign the "aryl" bands in your choice. 3000 1379 2920 1451 1605 A 3028 1496 696 729 4000 3000 2008 1000 VENUERI 3061 400 2961 B 1601 1590 1473 681 1071 770 4000 3000 eoce J000 DOST 00 2962 3061 430 1597 1481 1031 1 745 3000 2000 1000 RVENUMBERI 1614 3081 2961 D 50
7a. All of the following IR spectra are from arenes, but which one is likely from a monosubstituted alkyl benzene? (Circle the letter A, B, C, D; and see below.) Assign the "aryl" bands in your choice. 3000 1379 2920 1451 1605 A 3028 1496 696 729 4000 3000 2008 1000 VENUERI 3061 400 2961 B 1601 1590 1473 681 1071 770 4000 3000 eoce J000 DOST 00 2962 3061 430 1597 1481 1031 1 745 3000 2000 1000 RVENUMBERI 1614 3081 2961 D 50
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:## Identification of Monosubstituted Alkyl Benzene using IR Spectroscopy
The following IR spectra (A, B, C, and D) represent different arenes. The task is to determine which one likely belongs to a monosubstituted alkyl benzene.
### Analysis of Spectra
#### Spectrum A
- Peaks:
- 3028 cm^-1 (aromatic C-H stretch)
- 2920 cm^-1 (alkyl C-H stretch)
- 1605, 1496, 1451 cm^-1 (aromatic C=C stretches)
- 1379 cm^-1 (CH3 deformation)
- 729, 696 cm^-1 (out-of-plane aromatic C-H bending)
#### Spectrum B
- Peaks:
- 3061, 2961 cm^-1 (aromatic and alkyl C-H stretches)
- 1601, 1590 cm^-1 (aromatic C=C stretches)
- 1473 cm^-1 (C-H bend)
- 1071 cm^-1 (C-O stretch)
- 770, 681 cm^-1 (out-of-plane aromatic C-H bending)
- 400 cm^-1 (unknown)
#### Spectrum C
- Peaks:
- 3061, 2962 cm^-1 (aromatic and alkyl C-H stretches)
- 1597 cm^-1 (aromatic C=C stretches)
- 1481 cm^-1 (C-H bend)
- 1031 cm^-1 (C-O stretch)
- 745 cm^-1 (out-of-plane aromatic C-H bending)
- 430 cm^-1 (unknown)
#### Spectrum D
- Peaks:
- 3081, 2961 cm^-1 (aromatic and alkyl C-H stretches)
- 1614 cm^-1 (aromatic C=C stretches)
- 1487 cm^-1, others (C-H bend)
- 801 cm^-1 (out-of-plane aromatic C-H bending)
- 478 cm^-1 (unknown)
### Identifying Monosubstituted Alkyl Benzene
**Monosubstituted alkyl benzenes** typically show:
- Aromatic C-H stretching around 3030 cm^-1
- Alkyl C-H stretching around 2920 cm^-1
-
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