78. Under which conditions does nitrogen have the largest entropy per mole? N₂(s) at 50 K and 1 atm N₂0) at 70 K and 1 atm N₂(g) at 80 K and 1 atm N₂(g) at 80 K and 0.5 atm (A) (C) (B) (D)

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**Educational Transcription**

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**Question 74:**
A and B react exothermically to form a compound. A series of experiments is performed in which varying ratios of A to B are used, with a constant total number of moles, in each case. The observed temperature rise is plotted in the graph below. The simplest formula for the compound is probably:
- (A) A₃B₂
- (B) A₂B₃
- (C) AB₂
- (D) AB

**Graph Description:**
The graph plots the temperature rise (ΔT in °C) against the mole fraction of A. The temperature rise peaks at a mole fraction of A around 0.67 (approximately 0.67 on the x-axis or the ratio 2:1 of A:B). This suggests that the compound formed in this ratio exhibits the greatest exothermic reaction.

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**Question 75:**
If a 17.0 g sample of impure nickel metal reacts under standard conditions with 25.0 L of CO to form 6.25 L of Ni(CO)₄ gas, what is the percentage of Ni in the metal sample?

**Reaction:**
\[ \text{Ni}_{(\text{s})} + 4\text{CO}_{(\text{g})} \rightarrow \text{Ni(CO)}_4{_{(\text{g})}} \]

**Molar Masses:**
- Ni: 58.7 g·mol⁻¹
- Ni(CO)₄: 171. g·mol⁻¹

- (A) 24.1%
- (B) 25.0%
- (C) 96.4%
- (D) 100%

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**Thermochemistry Questions:**

**Question 76:**
Which molecule has the greatest bond energy?
- (A) H—Br
- (B) H—F
- (C) H—At
- (D) H—Cl
- (E) H—I

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**Question 77:**
For which process is the entropy change per mole the largest at constant temperature?
- (A) H₂O(l) → H₂O(g)
- (B) H₂O(s) → H₂O(g)
- (C) H₂O(s) → H₂O(l)
- (D)
Transcribed Image Text:**Educational Transcription** --- **Question 74:** A and B react exothermically to form a compound. A series of experiments is performed in which varying ratios of A to B are used, with a constant total number of moles, in each case. The observed temperature rise is plotted in the graph below. The simplest formula for the compound is probably: - (A) A₃B₂ - (B) A₂B₃ - (C) AB₂ - (D) AB **Graph Description:** The graph plots the temperature rise (ΔT in °C) against the mole fraction of A. The temperature rise peaks at a mole fraction of A around 0.67 (approximately 0.67 on the x-axis or the ratio 2:1 of A:B). This suggests that the compound formed in this ratio exhibits the greatest exothermic reaction. --- **Question 75:** If a 17.0 g sample of impure nickel metal reacts under standard conditions with 25.0 L of CO to form 6.25 L of Ni(CO)₄ gas, what is the percentage of Ni in the metal sample? **Reaction:** \[ \text{Ni}_{(\text{s})} + 4\text{CO}_{(\text{g})} \rightarrow \text{Ni(CO)}_4{_{(\text{g})}} \] **Molar Masses:** - Ni: 58.7 g·mol⁻¹ - Ni(CO)₄: 171. g·mol⁻¹ - (A) 24.1% - (B) 25.0% - (C) 96.4% - (D) 100% --- **Thermochemistry Questions:** **Question 76:** Which molecule has the greatest bond energy? - (A) H—Br - (B) H—F - (C) H—At - (D) H—Cl - (E) H—I --- **Question 77:** For which process is the entropy change per mole the largest at constant temperature? - (A) H₂O(l) → H₂O(g) - (B) H₂O(s) → H₂O(g) - (C) H₂O(s) → H₂O(l) - (D)
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