70 50 30 20 10 o+ 4000 3500 3000 295420m-1 2500 Ty 1437.50am-1 cm 1 1743.00-1 2000 1367.121 1500 1000 500

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Answer Choices (Only pick one):

 

1-bromobutane

 

1-cyclopropylethan-1-one

 

1-ethyl-3-methylbenzene

 

1,2-dimethoxynenzene

 

2,3-dimethylbutan-2-ol

 

3-methylbutan-1-ol

 

3,3-dimethylbutan-2-one

 

4-benzylpiperidine

 

4-methoxybenzaldehyde

 

acetic anhydride

 

acetonitrile

 

acetyl chloride

 

anisole

 

benzaldehyde

 

benzoic acid

 

benzophenone

 

benzyl acetate

 

bromobenzene

 

cyclohex-2-en-1-one

 

cyclohexanone

 

cyclopent-2-en-1-one

 

diethylamine

 

dimethyl malonate

 

ethyl 2-cyanoacetate

 

ethynylbenzene

 

heptanoic acid

 

methyl propionate

 

N-methylaniline

 

N,N-dimethylformamide

 

naphthalene

 

nitrobenzene

 

o-xylene

 

octan-1-amine

 

octan-1-ol

 

p-cresol

 

prop-2-en-1-ol

 

propan-2-one

 

propane-1,3-diol

 

tetrahydrofuran

 

toluene

This image depicts an infrared (IR) spectroscopy graph, showcasing the transmittance (%) versus the wavenumber (cm⁻¹). IR spectroscopy is a technique employed to identify functional groups in molecules by examining how they absorb infrared light.

### Key Components of the Graph:
- **X-Axis (Wavenumber, cm⁻¹)**: Ranges from 4000 cm⁻¹ to 500 cm⁻¹. The wavenumber is inversely proportional to wavelength and directly proportional to energy. Higher wavenumbers correspond to higher energy vibrational modes.
  
- **Y-Axis (% Transmittance)**: Varies from approximately 0% to 81%. Transmittance indicates the amount of light that passes through the sample, with lower values suggesting stronger absorption.

### Important Peaks:
1. **2896.14 cm⁻¹ and 2854.20 cm⁻¹**: These absorptions typically correspond to C-H stretching vibrations, often found in alkanes.
   
2. **1743.60 cm⁻¹**: This absorption is indicative of C=O stretching vibrations, which are characteristic of carbonyl groups like those in ketones, aldehydes, or esters.
   
3. **1437.56 cm⁻¹**: Possibly related to CH₂ bending vibrations, common in alkane chains.

4. **1367.12 cm⁻¹**: This may correspond to C-H bending vibrations found in methyl groups.

5. **1203.90 cm⁻¹**: Generally associated with C-O stretching in alcohols, ethers, or esters.

### Understanding the Graph:
The IR spectrum provides insights into the molecular structure by showcasing specific vibrational modes of bonds within the sample. Each peak signifies a specific type of bond or functional group, helping in the identification of the compound’s molecular composition.

This graph could be used for educational purposes to demonstrate how IR spectrometry functions as a tool in identifying chemical compounds and their structure based on their vibrational transitions.
Transcribed Image Text:This image depicts an infrared (IR) spectroscopy graph, showcasing the transmittance (%) versus the wavenumber (cm⁻¹). IR spectroscopy is a technique employed to identify functional groups in molecules by examining how they absorb infrared light. ### Key Components of the Graph: - **X-Axis (Wavenumber, cm⁻¹)**: Ranges from 4000 cm⁻¹ to 500 cm⁻¹. The wavenumber is inversely proportional to wavelength and directly proportional to energy. Higher wavenumbers correspond to higher energy vibrational modes. - **Y-Axis (% Transmittance)**: Varies from approximately 0% to 81%. Transmittance indicates the amount of light that passes through the sample, with lower values suggesting stronger absorption. ### Important Peaks: 1. **2896.14 cm⁻¹ and 2854.20 cm⁻¹**: These absorptions typically correspond to C-H stretching vibrations, often found in alkanes. 2. **1743.60 cm⁻¹**: This absorption is indicative of C=O stretching vibrations, which are characteristic of carbonyl groups like those in ketones, aldehydes, or esters. 3. **1437.56 cm⁻¹**: Possibly related to CH₂ bending vibrations, common in alkane chains. 4. **1367.12 cm⁻¹**: This may correspond to C-H bending vibrations found in methyl groups. 5. **1203.90 cm⁻¹**: Generally associated with C-O stretching in alcohols, ethers, or esters. ### Understanding the Graph: The IR spectrum provides insights into the molecular structure by showcasing specific vibrational modes of bonds within the sample. Each peak signifies a specific type of bond or functional group, helping in the identification of the compound’s molecular composition. This graph could be used for educational purposes to demonstrate how IR spectrometry functions as a tool in identifying chemical compounds and their structure based on their vibrational transitions.
**Title:** IR Spectra and Molecular Structure Identification

**Instructions:**
Assign the IR spectra given in Questions 1-3 to their corresponding structures from the options below.

**Molecular Structures:**

1. **Compound 1:** 
   - Structure: CH₃CH₂CH=CHCH₂OH (Allylic alcohol)
   - Functional Groups: Alcohol (OH), Alkene (C=C)

2. **Compound 2:** 
   - Structure: CH₃C₆H₅ (Methylbenzene)
   - Functional Groups: Aromatic ring

3. **Compound 3:** 
   - Structure: CH₃CH₂CH₂CH₃ (Butane)
   - Functional Groups: Alkane (C-H)

4. **Compound 4:**
   - Structure: CH₃C(=O)NH₂ (Acetamide)
   - Functional Groups: Amide (C=O, N-H)

5. **Compound 5:**
   - Structure: C₆H₅CH₂CN (Benzyl cyanide)
   - Functional Groups: Nitrile (C≡N)

6. **Compound 6:**
   - Structure: CH₃C(=O)OCH₃ (Methyl acetate)
   - Functional Groups: Ester (C=O, C-O)

7. **Compound 7:**
   - Structure: HO(CH₂)₆OH (Hexanediol)
   - Functional Groups: Diol (2x OH)

8. **Compound 8:**
   - Structure: C₆H₅C(=O)OH (Benzoic acid)
   - Functional Groups: Carboxylic acid (C=O, OH)

9. **Compound 9:**
   - Structure: CH₃OCH₂C₆H₅ (Phenyl methyl ether)
   - Functional Groups: Ether (C-O-C)

10. **Compound 10:**
    - Structure: CH₃(CH₂)₆OH (1-Octanol)
    - Functional Groups: Alcohol (OH)

11. **Compound 11:**
    - Structure: CH₃(CH₂)₄Br (Bromohexane)
    - Functional Groups: Alkyl halide (C-Br)

12. **Compound 12:**
    - Structure: CH₃
Transcribed Image Text:**Title:** IR Spectra and Molecular Structure Identification **Instructions:** Assign the IR spectra given in Questions 1-3 to their corresponding structures from the options below. **Molecular Structures:** 1. **Compound 1:** - Structure: CH₃CH₂CH=CHCH₂OH (Allylic alcohol) - Functional Groups: Alcohol (OH), Alkene (C=C) 2. **Compound 2:** - Structure: CH₃C₆H₅ (Methylbenzene) - Functional Groups: Aromatic ring 3. **Compound 3:** - Structure: CH₃CH₂CH₂CH₃ (Butane) - Functional Groups: Alkane (C-H) 4. **Compound 4:** - Structure: CH₃C(=O)NH₂ (Acetamide) - Functional Groups: Amide (C=O, N-H) 5. **Compound 5:** - Structure: C₆H₅CH₂CN (Benzyl cyanide) - Functional Groups: Nitrile (C≡N) 6. **Compound 6:** - Structure: CH₃C(=O)OCH₃ (Methyl acetate) - Functional Groups: Ester (C=O, C-O) 7. **Compound 7:** - Structure: HO(CH₂)₆OH (Hexanediol) - Functional Groups: Diol (2x OH) 8. **Compound 8:** - Structure: C₆H₅C(=O)OH (Benzoic acid) - Functional Groups: Carboxylic acid (C=O, OH) 9. **Compound 9:** - Structure: CH₃OCH₂C₆H₅ (Phenyl methyl ether) - Functional Groups: Ether (C-O-C) 10. **Compound 10:** - Structure: CH₃(CH₂)₆OH (1-Octanol) - Functional Groups: Alcohol (OH) 11. **Compound 11:** - Structure: CH₃(CH₂)₄Br (Bromohexane) - Functional Groups: Alkyl halide (C-Br) 12. **Compound 12:** - Structure: CH₃
Expert Solution
Step 1

IR spectra gives the information of functional groups of unknown compound.  

IR works based on the characteristic vibrational frequencies of functional groups.

 

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