1% 77- 701 60 50 40 30 20 10 -04 4000 3306.430m-1 3500 2020.44cm-1 3000 2556.70cm-1 2500 cm-1 1463.71cm-1 2000 1500 1978 19 1450.01cm-1 1050.55-1 1000 500

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Answer Choices (Only pick one):

 

1-bromobutane

 

1-cyclopropylethan-1-one

 

1-ethyl-3-methylbenzene

 

1,2-dimethoxynenzene

 

2,3-dimethylbutan-2-ol

 

3-methylbutan-1-ol

 

3,3-dimethylbutan-2-one

 

4-benzylpiperidine

 

4-methoxybenzaldehyde

 

acetic anhydride

 

acetonitrile

 

acetyl chloride

 

anisole

 

benzaldehyde

 

benzoic acid

 

benzophenone

 

benzyl acetate

 

bromobenzene

 

cyclohex-2-en-1-one

 

cyclohexanone

 

cyclopent-2-en-1-one

 

diethylamine

 

dimethyl malonate

 

ethyl 2-cyanoacetate

 

ethynylbenzene

 

heptanoic acid

 

methyl propionate

 

N-methylaniline

 

N,N-dimethylformamide

 

naphthalene

 

nitrobenzene

 

o-xylene

 

octan-1-amine

 

octan-1-ol

 

p-cresol

 

prop-2-en-1-ol

 

propan-2-one

 

propane-1,3-diol

 

tetrahydrofuran

 

toluene

This image presents an infrared (IR) spectroscopy graph, which plots the percentage of transmittance (%T) against the wavenumber (cm⁻¹). 

### Description and Analysis:

- **X-Axis (cm⁻¹):** Represents the wavenumber, ranging from 4000 cm⁻¹ to 500 cm⁻¹. Lower numbers on this axis correspond to longer wavelengths.

- **Y-Axis (%T):** Indicates the percentage of transmittance, ranging from 0% to 77%. Higher transmittance means less absorption of IR radiation at that particular wavenumber.

### Key Peaks and Their Positions:

1. **3306.43 cm⁻¹:** This peak generally indicates N-H or O-H stretching, common in alcohols, amines, or phenols.

2. **2925.44 cm⁻¹ and 2855.79 cm⁻¹:** These peaks are indicative of C-H stretching vibrations, typically found in alkanes or aliphatic compounds.

3. **1483.71 cm⁻¹:** This peak may correspond to C-H bending, often seen in alkanes.

4. **1374.44 cm⁻¹:** A peak in this region can suggest C-H bending, possibly from methyl groups.

5. **1465.01 cm⁻¹:** This also relates to C-H bending, confirming the presence of aliphatic groups.

6. **1058.55 cm⁻¹:** Generally associated with C-O stretching, likely indicating an ether or alcohol.

### Interpretation:

These peaks provide insight into the functional groups present in the molecule being analyzed. The spectral data can help characterize and identify unknown samples by comparing these peaks to known reference spectra. Understanding these kinds of absorption bands is crucial for fields such as organic chemistry and materials science.
Transcribed Image Text:This image presents an infrared (IR) spectroscopy graph, which plots the percentage of transmittance (%T) against the wavenumber (cm⁻¹). ### Description and Analysis: - **X-Axis (cm⁻¹):** Represents the wavenumber, ranging from 4000 cm⁻¹ to 500 cm⁻¹. Lower numbers on this axis correspond to longer wavelengths. - **Y-Axis (%T):** Indicates the percentage of transmittance, ranging from 0% to 77%. Higher transmittance means less absorption of IR radiation at that particular wavenumber. ### Key Peaks and Their Positions: 1. **3306.43 cm⁻¹:** This peak generally indicates N-H or O-H stretching, common in alcohols, amines, or phenols. 2. **2925.44 cm⁻¹ and 2855.79 cm⁻¹:** These peaks are indicative of C-H stretching vibrations, typically found in alkanes or aliphatic compounds. 3. **1483.71 cm⁻¹:** This peak may correspond to C-H bending, often seen in alkanes. 4. **1374.44 cm⁻¹:** A peak in this region can suggest C-H bending, possibly from methyl groups. 5. **1465.01 cm⁻¹:** This also relates to C-H bending, confirming the presence of aliphatic groups. 6. **1058.55 cm⁻¹:** Generally associated with C-O stretching, likely indicating an ether or alcohol. ### Interpretation: These peaks provide insight into the functional groups present in the molecule being analyzed. The spectral data can help characterize and identify unknown samples by comparing these peaks to known reference spectra. Understanding these kinds of absorption bands is crucial for fields such as organic chemistry and materials science.
**Transcription for Educational Website**

**Instructions:**
Assign the IR spectra given in Questions 1 - 3 to their corresponding structures from the ones below.

**Molecular Structures:**

1. Primary alcohol with an aldehyde group.
2. Ethylbenzene.
3. Triethylamine.
4. An amide with a benzene ring.
5. A long-chain alcohol with a ketone group.
6. A nitrile group attached to a benzene ring.
7. An amide with an isopropyl group.
8. A bromoalkane.
9. Benzoic acid.
10. An aromatic ester.
11. Hexanol.
12. An anisole derivative.
13. Ethylene glycol.
14. Phenylacetylene.
15. Isopropylbenzene.
16. Acetone.
17. Cyclohexanone.
18. T-butyl alcohol.
19. Acetophenone.

Each structure contains unique functional groups that can be identified using infrared spectroscopy, such as O-H, C=O, C-N, C-Br, etc. Use the given IR spectra characteristics to match them to these structures based on the presence and intensity of peaks corresponding to these functional groups.

**Note:** Diagrams contain only line structures of molecules without further elaboration on atomic labels or 3D conformation. Interpretation requires understanding of basic organic chemistry and IR spectroscopy.
Transcribed Image Text:**Transcription for Educational Website** **Instructions:** Assign the IR spectra given in Questions 1 - 3 to their corresponding structures from the ones below. **Molecular Structures:** 1. Primary alcohol with an aldehyde group. 2. Ethylbenzene. 3. Triethylamine. 4. An amide with a benzene ring. 5. A long-chain alcohol with a ketone group. 6. A nitrile group attached to a benzene ring. 7. An amide with an isopropyl group. 8. A bromoalkane. 9. Benzoic acid. 10. An aromatic ester. 11. Hexanol. 12. An anisole derivative. 13. Ethylene glycol. 14. Phenylacetylene. 15. Isopropylbenzene. 16. Acetone. 17. Cyclohexanone. 18. T-butyl alcohol. 19. Acetophenone. Each structure contains unique functional groups that can be identified using infrared spectroscopy, such as O-H, C=O, C-N, C-Br, etc. Use the given IR spectra characteristics to match them to these structures based on the presence and intensity of peaks corresponding to these functional groups. **Note:** Diagrams contain only line structures of molecules without further elaboration on atomic labels or 3D conformation. Interpretation requires understanding of basic organic chemistry and IR spectroscopy.
Expert Solution
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IR spectra provides the information of possible functional groups of unknown compound based on their characteristic vibrational frequencies.

 

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