7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per 100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution) as initiator in benzene at 60°C. What number-average degree of polymerization will be expected initially ? What fraction of the initiator will remain unused after 50% conversion of the monomer ? CAt 60°

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
6.7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per
100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution)
as initiator in benzene at 60°C. What number-average degree of polymerization will
be expected initially ? What fraction of the initiator will remain unused after 50%
conversion of the monomer ? [At 60°C, kd = 4.47x10-6 s; k/k, = 10-2 L/mol-
s; f = 0.4; termination occurs by both disproportionation (58%) and coupling
(42%).]
[Ans. 24.7 h; 739; 0.67]
Transcribed Image Text:6.7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per 100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution) as initiator in benzene at 60°C. What number-average degree of polymerization will be expected initially ? What fraction of the initiator will remain unused after 50% conversion of the monomer ? [At 60°C, kd = 4.47x10-6 s; k/k, = 10-2 L/mol- s; f = 0.4; termination occurs by both disproportionation (58%) and coupling (42%).] [Ans. 24.7 h; 739; 0.67]
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 5 images

Blurred answer
Knowledge Booster
Types of Polymers on the Basis of Method of Preparation
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY