7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per 100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution) as initiator in benzene at 60°C. What number-average degree of polymerization will be expected initially ? What fraction of the initiator will remain unused after 50% conversion of the monomer ? CAt 60°
7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per 100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution) as initiator in benzene at 60°C. What number-average degree of polymerization will be expected initially ? What fraction of the initiator will remain unused after 50% conversion of the monomer ? CAt 60°
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![6.7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per
100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution)
as initiator in benzene at 60°C. What number-average degree of polymerization will
be expected initially ? What fraction of the initiator will remain unused after 50%
conversion of the monomer ? [At 60°C, kd = 4.47x10-6 s; k/k, = 10-2 L/mol-
s; f = 0.4; termination occurs by both disproportionation (58%) and coupling
(42%).]
[Ans. 24.7 h; 739; 0.67]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe2cc9671-f29f-431a-8ba6-46900876224a%2Feb6f482a-b82f-41ee-a09e-156d253f950f%2F4uh1tel_processed.jpeg&w=3840&q=75)
Transcribed Image Text:6.7 Calculate the time needed to convert half of charge of methyl methacrylate (10 g per
100 mL solution) to polymer using benzoyl peroxide (0.1 g per 100 mL solution)
as initiator in benzene at 60°C. What number-average degree of polymerization will
be expected initially ? What fraction of the initiator will remain unused after 50%
conversion of the monomer ? [At 60°C, kd = 4.47x10-6 s; k/k, = 10-2 L/mol-
s; f = 0.4; termination occurs by both disproportionation (58%) and coupling
(42%).]
[Ans. 24.7 h; 739; 0.67]
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