7 3) Complete the cycle below which pertains to the Ni-catalyzed Kumada-Corriu Cross-Coupling that furnishes C(sp3)-C(sp³) bonds: R R' -n L L„Ni(0) r 2 1 3 MgX+ Ni(II) R 6 5 4 Tasks: Draw the structural formulas of 1 (a common C4 building block) and 2 (a neutral 16 electron species that only contains organic ligands). What reaction(s) is (are) involved in the conversion 1 → 2? Identify the chemical species 3, 4, 5, and 7. Give the valence electron count of Ni in compound 6 (apply the ionic model). What reaction(s) is (are) involved in the conversion 6 → 2?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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7
3) Complete the cycle below which pertains to the Ni-catalyzed Kumada-Corriu Cross-Coupling that
furnishes C(sp3)-C(sp³) bonds:
R
R'
-n L
L„Ni(0)
r
2
1
3
MgX+
Ni(II)
R
6
5
4
Tasks:
Draw the structural formulas of 1 (a common C4 building block) and 2 (a neutral 16 electron species
that only contains organic ligands). What reaction(s) is (are) involved in the conversion 1 → 2? Identify
the chemical species 3, 4, 5, and 7. Give the valence electron count of Ni in compound 6 (apply the
ionic model). What reaction(s) is (are) involved in the conversion 6 → 2?
Transcribed Image Text:7 3) Complete the cycle below which pertains to the Ni-catalyzed Kumada-Corriu Cross-Coupling that furnishes C(sp3)-C(sp³) bonds: R R' -n L L„Ni(0) r 2 1 3 MgX+ Ni(II) R 6 5 4 Tasks: Draw the structural formulas of 1 (a common C4 building block) and 2 (a neutral 16 electron species that only contains organic ligands). What reaction(s) is (are) involved in the conversion 1 → 2? Identify the chemical species 3, 4, 5, and 7. Give the valence electron count of Ni in compound 6 (apply the ionic model). What reaction(s) is (are) involved in the conversion 6 → 2?
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