21. The following statements concern the affect of concentration, pressure, temperature, and other factors on the amount of SO3 present when the reaction 2 SO2(g) + 1O2(g) 2 2 SO3(g) reaches equilibrium. Which one of these statements is incorrect? A. Lowering the temperature increases the amount of SO3 that is produced. B. The amount of SO3 produced will be bigger if pure O2 is used instead of ordinary air. (Air is a 4 to 1 mixture of N2 and O2, respectively.) C. Removing SO3 as it is produced will "shift the reaction to the right" and produce more SO3. D. The catalyst, V½O5, has no effect on the equilibrium concentration of SO3. E. Increasing pressure (by decreasing volume) has no effect on the amount of SO3 produced.

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Chapter1: Chemical Foundations
Section: Chapter Questions
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19. The reaction 2 SO2(8) + 102(g) 22 SO3(8) is exothermic. Which of the following statements is
correct concerning the effect of lowering the temperature on the values of: Kc is the equilibrium
constant; kf and kr are the forward and reverse rate constants. Symbols: ↑, increases; , decreases; = no
change.
Kc
kf
kr
А.
C.
D.
20. The reaction 2 SO2(g) + 102(g) 2 2 S03(g) is exothermic. Which of the following statements is
correct concerning the effect of a catalyst on the values of: Kç is the equilibrium constant; Ea is the
activation energy; and AH° is the enthalpy difference between the reactants and products. Symbols: 1,
increases; V, decreases; = no change.
K.
Ea
ΔΗ.
А.
В.
С.
D.
21. The following statements concern the affect of concentration, pressure, temperature, and other
factors on the amount of SO3 present when the reaction 2 SO2(g) + 102(g) 2 2 SO3(g) reaches
equilibrium. Which one of these statements is incorrect?
A. Lowering the temperature increases the amount of SO3 that is produced.
The amount of SO3 produced will be bigger if pure O2 is used instead of ordinary air. (Air is a 4 to
1 mixture of N2 and O2, respectively.)
В.
C. Removing SO3 as it is produced will "shift the reaction to the right" and produce more SO3.
D. The catalyst, V2O5, has no effect on the equilibrium concentration of SO3.
E. Increasing pressure (by decreasing volume) has no effect on the amount of SO3 produced.
B.
Transcribed Image Text:19. The reaction 2 SO2(8) + 102(g) 22 SO3(8) is exothermic. Which of the following statements is correct concerning the effect of lowering the temperature on the values of: Kc is the equilibrium constant; kf and kr are the forward and reverse rate constants. Symbols: ↑, increases; , decreases; = no change. Kc kf kr А. C. D. 20. The reaction 2 SO2(g) + 102(g) 2 2 S03(g) is exothermic. Which of the following statements is correct concerning the effect of a catalyst on the values of: Kç is the equilibrium constant; Ea is the activation energy; and AH° is the enthalpy difference between the reactants and products. Symbols: 1, increases; V, decreases; = no change. K. Ea ΔΗ. А. В. С. D. 21. The following statements concern the affect of concentration, pressure, temperature, and other factors on the amount of SO3 present when the reaction 2 SO2(g) + 102(g) 2 2 SO3(g) reaches equilibrium. Which one of these statements is incorrect? A. Lowering the temperature increases the amount of SO3 that is produced. The amount of SO3 produced will be bigger if pure O2 is used instead of ordinary air. (Air is a 4 to 1 mixture of N2 and O2, respectively.) В. C. Removing SO3 as it is produced will "shift the reaction to the right" and produce more SO3. D. The catalyst, V2O5, has no effect on the equilibrium concentration of SO3. E. Increasing pressure (by decreasing volume) has no effect on the amount of SO3 produced. B.
Questions 15-21 concern the reaction 2 SO2(8) + 102(8) 22 SO3(g), the crucial step in the
production of sulfuric acid. For this reaction AH° = -198 kJ/mol and AS° = -0.187 kJ/mol·K. SO2
(perhaps from the production of copper metal) is mixed with air and heated, resulting in the formation
of SO3. (All concentrations are in Kolks units.)
Transcribed Image Text:Questions 15-21 concern the reaction 2 SO2(8) + 102(8) 22 SO3(g), the crucial step in the production of sulfuric acid. For this reaction AH° = -198 kJ/mol and AS° = -0.187 kJ/mol·K. SO2 (perhaps from the production of copper metal) is mixed with air and heated, resulting in the formation of SO3. (All concentrations are in Kolks units.)
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