682 APPENDIX B. Properties of Pure Species Table B.2: Constants for the Antoine Equation for Vapor Pressures of Pure Species B In P sat /kPa = A t/°C+C Latent heat of vaporization at the normal boiling point (AHn), and normal boiling point (t) Parameters for Antoine Eqn. AT Temp. Range ΔΗ. KJ/mol eFormula °C Name В C 228.060 -26 77 C3H60 C2H402 C2H3N C6H6 САН10 n-Butane IEC4H10 CerCaHioo 2-Butanol Cres C4H10O HC4H100 C4H100 Carbon tetrachloride CCI4 Acetone 14.3145 2756.22 3580.80 3413.10 29.10 56.2 117.9 142 15.0717 14.8950 13.7819 2726.81 13.8254 13.6608 15.3144 15.1989 Acetic acid 224.650 24 23.70 182 Acetonitrile 250.523 217.572 -27 81 30.19 81.6 6 104 83-7 -73 19 37 138 25 120 30-128 Benzene 30.72 80.0 iso-Butane 2181.79 248.870 21.30 -11.9 2154.70 238.789 22.44 -0.5 1-Butanol 3212.43 182.739 43.29 117.6 3026.03 186.500 40.75 99.5 107.8 iso-Butanol tert-Butanol 14.6047 14.8445 14.0572 2740.95 166.670 41.82 2658.29 177.650 10-101 39.07 82.3 232.148 211.700 2914.23 -14-101 29.82 76.6 Chlorobenzene 13.8635 29 159 35.19 131.7 C6H5CI САНоС1 СHC3 C6H12 C5H10 281 C10H22 3174.78 1-Chlorobutane 79 13.7965 13.7324 2723.73 218.265 17 30.39 78.5 218.552 220.618 Chloroform 2548.74 23 84 29.24 61.1 9 105 29.97 Cyclohexane Cyclopentane n-Decane 13.6568 80.7 2723.44 2653.90 234.510 193.858 13.9727 -35-71 27.30 49.2 3442.76 2463.93 2511.29 13.9748 65 203 38.75 174.1 13.9891 14.0735 15.0967 -38 -43 20 105 208379 60 28.06 Dichloromethane CH2Cl2 C4HI0O 1,4-Dioxane 20 C4HgO2 0eC20H42 CэНоо C8H10 C2Н602 C7H16 C6H14 CH40 CзНо02 C4H&O CH3NO2 CoH20 C&H18 C8H18 C$H12 С6Н6О CзHg0 СзHяО C7H8 Нао C&H10 C8H10 REC8H10 223.240 39.7 Diethyl ether 231.200 55 26.52 34.4 240.337 132.100 230.918 3579.78 34.16 101.3 n-Eicosane 14.4575 4680.46 57.49 343.6 38.56 35.57 96 78.2 16.8958 13.9726 3259.93 4187.46 Ethanol 3795.17 33-163 100 4 123 212.300 136.2 Ethylbenzene Ethylene glycol* n-Heptane n-Hexane 15.7567 178.650 222 50.73 197.3 13.8622 13.8193 98. 68. 35.21 64. 2910.26 216.432 31.77 2696.04 3638.27 224.317 -19-92 28.85 Methanol 16.5785 239.500 -11-83 -23-78 -8-103 2662.78 219.690 30.32 56. Methyl acetate Methyl ethyl ketone Nitromethane 14.2456 31.30 33.99 79. 14.1334 14.7513 2838.24 3331.70 218.690 56 146 46 178 2 125 152 227.600 101. n-Nonane 13.9854 3311.19 202.694 36.91 150 30.79 99 13.6703 13.9346 iso-Octane ER 2896.31 220.767 34.41 125 209.635 232.014 n-Octane 3123.13 26 040 00 n-Pentane 13.7667 2451.88 -45 58 25.79 36 46.18 181 Phenol 1-Propanol 2-Propanol 14.4387 3507.80 175.400 80 208 3483.67 3640.20 41.44 39.85 16.1154 205.807 20 116 16.6796 219.610 100 33.18 40.66 36.24 Toluene 13.9320 3056.96 217.625 13 136 11 Water 682 16.3872 10 3885.70 230.170 0-200 o-Xylene т-Хylene р-Хylene 14.0415 3358.79 212.041 40 172 14 13 35 166 35 166 35.66 14.1387 14.0579 3381.81 216.120 3331.45 214.627 35.67 13 Based primarily on data presented by B. E. Poling, J. M. Prausnitz, and J. P. O'Connell, The Properties of Gases and Liquids, 5th ed., App. A, McGraw-Hill, New York, 2001. bias b *Antoine parameters adapted from Gmehling et al. See footnote 2, p. 791. Antoine parameters A are adjusted to reproduce the listed values of tn

682 APPENDIX B. Properties of Pure Species Table B.2: Constants for the Antoine Equation for Vapor Pressures of Pure Species B In P sat /kPa = A t/°C+C Latent heat of vaporization at the normal boiling point (AHn), and normal boiling point (t) Parameters for Antoine Eqn. AT Temp. Range ΔΗ. KJ/mol eFormula °C Name В C 228.060 -26 77 C3H60 C2H402 C2H3N C6H6 САН10 n-Butane IEC4H10 CerCaHioo 2-Butanol Cres C4H10O HC4H100 C4H100 Carbon tetrachloride CCI4 Acetone 14.3145 2756.22 3580.80 3413.10 29.10 56.2 117.9 142 15.0717 14.8950 13.7819 2726.81 13.8254 13.6608 15.3144 15.1989 Acetic acid 224.650 24 23.70 182 Acetonitrile 250.523 217.572 -27 81 30.19 81.6 6 104 83-7 -73 19 37 138 25 120 30-128 Benzene 30.72 80.0 iso-Butane 2181.79 248.870 21.30 -11.9 2154.70 238.789 22.44 -0.5 1-Butanol 3212.43 182.739 43.29 117.6 3026.03 186.500 40.75 99.5 107.8 iso-Butanol tert-Butanol 14.6047 14.8445 14.0572 2740.95 166.670 41.82 2658.29 177.650 10-101 39.07 82.3 232.148 211.700 2914.23 -14-101 29.82 76.6 Chlorobenzene 13.8635 29 159 35.19 131.7 C6H5CI САНоС1 СHC3 C6H12 C5H10 281 C10H22 3174.78 1-Chlorobutane 79 13.7965 13.7324 2723.73 218.265 17 30.39 78.5 218.552 220.618 Chloroform 2548.74 23 84 29.24 61.1 9 105 29.97 Cyclohexane Cyclopentane n-Decane 13.6568 80.7 2723.44 2653.90 234.510 193.858 13.9727 -35-71 27.30 49.2 3442.76 2463.93 2511.29 13.9748 65 203 38.75 174.1 13.9891 14.0735 15.0967 -38 -43 20 105 208379 60 28.06 Dichloromethane CH2Cl2 C4HI0O 1,4-Dioxane 20 C4HgO2 0eC20H42 CэНоо C8H10 C2Н602 C7H16 C6H14 CH40 CзНо02 C4H&O CH3NO2 CoH20 C&H18 C8H18 C$H12 С6Н6О CзHg0 СзHяО C7H8 Нао C&H10 C8H10 REC8H10 223.240 39.7 Diethyl ether 231.200 55 26.52 34.4 240.337 132.100 230.918 3579.78 34.16 101.3 n-Eicosane 14.4575 4680.46 57.49 343.6 38.56 35.57 96 78.2 16.8958 13.9726 3259.93 4187.46 Ethanol 3795.17 33-163 100 4 123 212.300 136.2 Ethylbenzene Ethylene glycol* n-Heptane n-Hexane 15.7567 178.650 222 50.73 197.3 13.8622 13.8193 98. 68. 35.21 64. 2910.26 216.432 31.77 2696.04 3638.27 224.317 -19-92 28.85 Methanol 16.5785 239.500 -11-83 -23-78 -8-103 2662.78 219.690 30.32 56. Methyl acetate Methyl ethyl ketone Nitromethane 14.2456 31.30 33.99 79. 14.1334 14.7513 2838.24 3331.70 218.690 56 146 46 178 2 125 152 227.600 101. n-Nonane 13.9854 3311.19 202.694 36.91 150 30.79 99 13.6703 13.9346 iso-Octane ER 2896.31 220.767 34.41 125 209.635 232.014 n-Octane 3123.13 26 040 00 n-Pentane 13.7667 2451.88 -45 58 25.79 36 46.18 181 Phenol 1-Propanol 2-Propanol 14.4387 3507.80 175.400 80 208 3483.67 3640.20 41.44 39.85 16.1154 205.807 20 116 16.6796 219.610 100 33.18 40.66 36.24 Toluene 13.9320 3056.96 217.625 13 136 11 Water 682 16.3872 10 3885.70 230.170 0-200 o-Xylene т-Хylene р-Хylene 14.0415 3358.79 212.041 40 172 14 13 35 166 35 166 35.66 14.1387 14.0579 3381.81 216.120 3331.45 214.627 35.67 13 Based primarily on data presented by B. E. Poling, J. M. Prausnitz, and J. P. O'Connell, The Properties of Gases and Liquids, 5th ed., App. A, McGraw-Hill, New York, 2001. bias b *Antoine parameters adapted from Gmehling et al. See footnote 2, p. 791. Antoine parameters A are adjusted to reproduce the listed values of tn

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

See similar textbooks

Related questions

Question

Ten moles per second (10 mol/s) of an equimolar liquid mixture of water (1)/ethanol
(2) at 30 °C and 11 kPa is flashed to 7.0 kPa. Assume that the Raoult’s Law is
appropriate for this mixture using.
[i] Prove that the given pressure lies between the bubble P (Pbubbl) and dew P
(Dewdew) and the liquid system will partially flash, allowing a separation to
occur.
[ii] What is the resulting composition and molar flow rate of the equilibrium
streams exiting the flash distillation unit?
Note that Antoine equation, with parameters are provided in Appendix B.2, page 682
in the textbook.

682
APPENDIX B. Properties of Pure Species
Table B.2: Constants for the Antoine Equation for Vapor Pressures of Pure Species
B
In P sat /kPa = A
t/°C+C
Latent heat of vaporization at the normal boiling point (AHn), and normal boiling point (t)
Parameters for Antoine Eqn.
AT
Temp. Range
ΔΗ.
KJ/mol
eFormula
°C
Name
В
C
228.060
-26
77
C3H60
C2H402
C2H3N
C6H6
САН10
n-Butane IEC4H10
CerCaHioo
2-Butanol Cres C4H10O
HC4H100
C4H100
Carbon tetrachloride CCI4
Acetone
14.3145
2756.22
3580.80
3413.10
29.10
56.2
117.9
142
15.0717
14.8950
13.7819 2726.81
13.8254
13.6608
15.3144
15.1989
Acetic acid
224.650
24
23.70
182
Acetonitrile
250.523
217.572
-27
81
30.19
81.6
6 104
83-7
-73 19
37 138
25 120
30-128
Benzene
30.72
80.0
iso-Butane
2181.79
248.870
21.30
-11.9
2154.70
238.789
22.44
-0.5
1-Butanol
3212.43
182.739
43.29
117.6
3026.03
186.500
40.75
99.5
107.8
iso-Butanol
tert-Butanol
14.6047
14.8445
14.0572
2740.95
166.670
41.82
2658.29
177.650
10-101
39.07
82.3
232.148
211.700
2914.23
-14-101
29.82
76.6
Chlorobenzene
13.8635
29
159
35.19
131.7
C6H5CI
САНоС1
СHC3
C6H12
C5H10
281 C10H22
3174.78
1-Chlorobutane
79
13.7965
13.7324
2723.73
218.265
17
30.39
78.5
218.552
220.618
Chloroform
2548.74
23
84
29.24
61.1
9
105
29.97
Cyclohexane
Cyclopentane
n-Decane
13.6568
80.7
2723.44
2653.90
234.510
193.858
13.9727
-35-71
27.30
49.2
3442.76
2463.93
2511.29
13.9748
65
203
38.75
174.1
13.9891
14.0735
15.0967
-38
-43
20 105
208379
60
28.06
Dichloromethane CH2Cl2
C4HI0O
1,4-Dioxane 20 C4HgO2
0eC20H42
CэНоо
C8H10
C2Н602
C7H16
C6H14
CH40
CзНо02
C4H&O
CH3NO2
CoH20
C&H18
C8H18
C$H12
С6Н6О
CзHg0
СзHяО
C7H8
Нао
C&H10
C8H10
REC8H10
223.240
39.7
Diethyl ether
231.200
55
26.52
34.4
240.337
132.100
230.918
3579.78
34.16
101.3
n-Eicosane
14.4575
4680.46
57.49
343.6
38.56
35.57
96
78.2
16.8958
13.9726 3259.93
4187.46
Ethanol
3795.17
33-163
100
4 123
212.300
136.2
Ethylbenzene
Ethylene glycol*
n-Heptane
n-Hexane
15.7567
178.650
222
50.73
197.3
13.8622
13.8193
98.
68.
35.21 64.
2910.26
216.432
31.77
2696.04
3638.27
224.317
-19-92
28.85
Methanol
16.5785
239.500
-11-83
-23-78
-8-103
2662.78
219.690
30.32
56.
Methyl acetate
Methyl ethyl ketone
Nitromethane
14.2456
31.30
33.99
79.
14.1334
14.7513
2838.24
3331.70
218.690
56 146
46 178
2 125
152
227.600
101.
n-Nonane
13.9854
3311.19
202.694
36.91
150
30.79
99
13.6703
13.9346
iso-Octane
ER
2896.31
220.767
34.41
125
209.635
232.014
n-Octane
3123.13
26
040
00
n-Pentane
13.7667
2451.88
-45
58
25.79
36
46.18
181
Phenol
1-Propanol
2-Propanol
14.4387
3507.80
175.400
80
208
3483.67
3640.20
41.44
39.85
16.1154
205.807
20
116
16.6796
219.610
100
33.18
40.66
36.24
Toluene
13.9320
3056.96
217.625
13 136
11
Water
682
16.3872
10
3885.70
230.170
0-200
o-Xylene
т-Хylene
р-Хylene
14.0415
3358.79
212.041
40
172
14
13
35 166
35 166
35.66
14.1387
14.0579
3381.81
216.120
3331.45
214.627
35.67 13
Based primarily on data presented by B. E. Poling, J. M. Prausnitz, and J. P. O'Connell,
The Properties of Gases and Liquids, 5th ed., App. A, McGraw-Hill, New York, 2001.
bias
b
*Antoine parameters adapted from Gmehling et al. See footnote 2, p. 791.
Antoine parameters A are adjusted to reproduce the listed values of tn

Expert Solution

Trending now

This is a popular solution!

Step by step

Solved in 9 steps with 8 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.

Recommended textbooks for you

Introduction to Chemical Engineering Thermodynami…

Chemical Engineering

ISBN:

9781259696527

Author:

J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:

McGraw-Hill Education