6.5. The apparatus shown here 1s used to measure the vapor pressure of ethylene diamine. CONSTANT- *TEMPERATURE BATH ` Liquid Vapor The system is loaded with pure ethylene diamine and the bath is adjusted to each of several known temperatures. The following readings are taken on a day when the atmospheric pressure is 758.9 mmHg: Mercury Level T(°C) Right Arm (mm) 42.7 Left Arm (mm) 138 862 58.9 68.3 160 840 182 818 213 262 77.9 787 88.6 738 98.3 323 677 105.8 383 617

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### Measuring Vapor Pressure of Ethylene Diamine

#### Apparatus Description
The diagram illustrates the apparatus used to measure the vapor pressure of ethylene diamine. The setup involves a constant-temperature bath that maintains the ethylene diamine at various known temperatures. As the ethylene diamine heats, it transitions between liquid and vapor phases.

#### Experiment Procedure
The system is loaded with pure ethylene diamine, and the bath is adjusted to each of several specified temperatures. On the day of the experiment, the atmospheric pressure is recorded as 758.9 mmHg.

**Observations**

| Temperature (°C) | Mercury Level Right Arm (mm) | Mercury Level Left Arm (mm) |
|------------------|-------------------------------|-----------------------------|
| 42.7             | 138                           | 862                         |
| 58.9             | 160                           | 840                         |
| 68.3             | 182                           | 818                         |
| 77.9             | 213                           | 787                         |
| 88.6             | 262                           | 738                         |
| 98.3             | 323                           | 677                         |
| 105.8            | 383                           | 617                         |

#### Explanation
The table lists the mercury levels in the right and left arms of the manometer at various temperatures. These readings reflect the vapor pressure exerted by the ethylene diamine at each temperature. The difference in mercury levels between the two arms indicates the pressure exerted by the ethylene diamine vapor.

This data is crucial for understanding how vapor pressure varies with temperature, which is fundamental for applications in chemical engineering and thermodynamics.
Transcribed Image Text:### Measuring Vapor Pressure of Ethylene Diamine #### Apparatus Description The diagram illustrates the apparatus used to measure the vapor pressure of ethylene diamine. The setup involves a constant-temperature bath that maintains the ethylene diamine at various known temperatures. As the ethylene diamine heats, it transitions between liquid and vapor phases. #### Experiment Procedure The system is loaded with pure ethylene diamine, and the bath is adjusted to each of several specified temperatures. On the day of the experiment, the atmospheric pressure is recorded as 758.9 mmHg. **Observations** | Temperature (°C) | Mercury Level Right Arm (mm) | Mercury Level Left Arm (mm) | |------------------|-------------------------------|-----------------------------| | 42.7 | 138 | 862 | | 58.9 | 160 | 840 | | 68.3 | 182 | 818 | | 77.9 | 213 | 787 | | 88.6 | 262 | 738 | | 98.3 | 323 | 677 | | 105.8 | 383 | 617 | #### Explanation The table lists the mercury levels in the right and left arms of the manometer at various temperatures. These readings reflect the vapor pressure exerted by the ethylene diamine at each temperature. The difference in mercury levels between the two arms indicates the pressure exerted by the ethylene diamine vapor. This data is crucial for understanding how vapor pressure varies with temperature, which is fundamental for applications in chemical engineering and thermodynamics.
**Exercise on Ethylene Diamine Thermodynamics**

a) Calculate \( p^* \) for ethylene diamine at each temperature.

b) Use a semilog plot of \( p^* \) versus \( 1/T \) to estimate the normal boiling point and the heat of vaporization of ethylene diamine.

c) Does the Clausius–Clapeyron equation appear to be justified for ethylene diamine in the temperature range covered by the data? Explain.
Transcribed Image Text:**Exercise on Ethylene Diamine Thermodynamics** a) Calculate \( p^* \) for ethylene diamine at each temperature. b) Use a semilog plot of \( p^* \) versus \( 1/T \) to estimate the normal boiling point and the heat of vaporization of ethylene diamine. c) Does the Clausius–Clapeyron equation appear to be justified for ethylene diamine in the temperature range covered by the data? Explain.
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