**Problem 6-10**BaCl₂·H₂O(s) loses water when it is heated in an oven:\[ \text{BaCl}_2 \cdot \text{H}_2\text{O(s)} \rightarrow \text{BaCl}_2\text{(s)} + \text{H}_2\text{O(g)} \]\[\Delta H^\circ = 63.11 \, \text{kJ/mol at } 25^\circ \text{C}\]\[\Delta S^\circ = +148 \, \text{J/(K} \cdot \text{mol) at } 25^\circ \text{C}\](a) **Write the equilibrium constant for this reaction. Calculate the vapor pressure of gaseous H₂O (\( P_{\text{H}_2\text{O}} \)) above BaCl₂·H₂O at 298 K.**(b) **If \(\Delta H^\circ\) and \(\Delta S^\circ\) are not temperature dependent (a poor assumption), estimate the temperature at which \( P_{\text{H}_2\text{O}} \) above BaCl₂·H₂O(s) will be 1 bar.****Graph/Diagram Explanation:** There are no graphs or diagrams in this problem. The question involves thermodynamic calculations related to the equilibrium constant and changes in enthalpy and entropy for a chemical reaction.

Given : BaCl2.H2O(s) ⇌ BaCl2(s)+H2O ∆H°=63.11 kJ/mol at 25°C…

6-10. BaCl2 H2O(s) loses water when it is heated in an oven: BaCl2 • H20(s) = = BaCl2(s) + H20(g) AH° = 63.11 kJ/mol at 25°C %3D AS° = +148 J/(K• mol) at 25°C (a) Write the equilibrium constant for this reaction. Calculate the vapor pressure of gaseous H2O (PH,0) above BaCl2 H2O at 298 K. (b) If AH° and AS° are not temperature dependent (a poor assump- tion), estimate the temperature at which PH0 above BaCl, H,O(s) will be 1 bar.

6-10. BaCl2 H2O(s) loses water when it is heated in an oven: BaCl2 • H20(s) = = BaCl2(s) + H20(g) AH° = 63.11 kJ/mol at 25°C %3D AS° = +148 J/(K• mol) at 25°C (a) Write the equilibrium constant for this reaction. Calculate the vapor pressure of gaseous H2O (PH,0) above BaCl2 H2O at 298 K. (b) If AH° and AS° are not temperature dependent (a poor assump- tion), estimate the temperature at which PH0 above BaCl, H,O(s) will be 1 bar.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Please don't provide hand written solution.....
Given that Ka for HIO is 3.2 × 10-1" at 25 °C, what is the value of K, for IO¯ at 25 °C? Kp = Given that Kp for CH, NH, is 5.0 x 10-4 at 25 °C, what is the value of Ka for CH, NH; at 25 °C? Ka =
1. For the system H₂(g) ΔΗ = -9.4 kJ K = 62.5 at 800 K. What is the equilibrium constant at 333 °C? + 1₂(g) → 2HI(g)
Consider the following chemical reaction: C3H8 + 5 O2 <==> 3 CO2 + 4 H2O This reaction was determined to have a Kp = 2.00 * 103 at a temperature of 20 °C . What is the value of Kc for this reaction? (Please provide your answer to 3 significant figures)
• Question 6 Calculate AH° for the process Hg2Cl2(s)→ 2Hg(l) + Cl2(g) from the following information AH° = -162.0 K/mol Hg() + Clɔ(g) → HgClɔ(s) AH° = -250.3 Kmol Hg() + HgCl2(s) –→ Hg2Cl>(s) /mol
The equilibrium constant for the chemical equation N2(g)+3H2(g)↽−−⇀2NH3(g) N 2 ⁡ ( g ) + 3 ⁢ H 2 ⁡ ( g ) ⁢ ↽ − − ⇀ ⁢ 2 ⁢ NH3(g) is Kp = 0.249 at 253 ∘C. 253 ⁢∘ C. Calculate the value of Kc for the reaction at 253 ∘C
Consider the following reaction where K, = 9.52×10-2 at 350 K: %3D CH4(g) + CC14(g) 2CH2C1½(g) If the three gases are mixed in a rigid container at 350 K so that the partial pressure of each gas is initially one atm, what will happen? Indicate True (T) or False (F) for each of the following: • 1. A reaction will occur in which CH,Cl2(g) is consumed. v 2. K, will increase. • 3. A reaction will occur in which CH, is consumed. • 4. Q is less than K. v 5. The reaction is at equilibrium. No further reaction will occur.
Use the data in the supporting materials to calculate the equilibrium constant (Kp) for the following reaction at 25°C. 2 SO2(g) + O2(g) =2 S03(g) Кра 4.24e24 Calculate Kp for the reaction at 49°C using the following equations. (a) the van't Hoff equation below. (P), A,H° RT? a In K Кр = 1.138e22 (b) the Gibbs-Helmholtz equations below to find A-G° at 49°C and hence, Kp at the same temperature. AG ΔΗ (i) = - T2 A-G2 A;G1 1 (ii) T2 T1 T1 Kp = 1.138e22 (c) A-G° = ArH° – TA¡S° to find A-G° at 49°C and hence, Kp at the same temperature. Кр 3D 1.7742е22 State the approximations employed in each case. The assumption that A,H° is temperature independent and equal to the value calculated at 298.15 K is required by all three parts A second assumption that AS° is temperature independent and equal to the value calculated at 298.15 K is required by part (c) Compare your results. The answers calculated in parts (a) and (b) ▼ in part (c) are very close as expected because the formulas used to…
Calculate the reaction quotient, Qr for the following reactions and conditions: 7. 2 SO3(g) 2 SO2(g) + O2(g) 16.5; Pso3 = 0.45 atm; Pso2 = 1.52 atm; : Кр- %3D Po2 = 0.210 atm 8. 2 NO(g) + Cl2(g) → 2 NOCI(g) : Кр- 2.5 x 103; PNo = 0.0032 atm; Pc12 = 0.023 atm; PNOCI = 0.210 atm 9.2 NH3(g) N2(g) + 3H2(g) : Кр- 17.0; PNH3 = 0.13 atm; PN2 = 0.34 atm; |3D PH2 = 1.1 atm %3D 10. Will the system in Question 7 proceed to reactants or products for the conditions given? 11. Will the system in Question 8 proceed to reactants or products for the conditions given? 12. Will the system in Question 9 proceed to reactants or products for the conditions given? 13. For the chemical reaction in Question 7, if it is at equilibrium which direction will it shift if SO2 is added? 14. For the chemical reaction in Question 8, if it is at equilibrium which direction will it shift if NO is removed? 15. For the chemical reaction in Question 9, if it is at equilibrium, which direction will if shift if all the…
Do not give handwriting solution.