5.4 Using Equation 5.10, calculate the limiting current density for a fuel cell cathode running on air at STP. Assume only O2 and N2 and ignore the presence of water vapor. Assume that the diffusion layer is 500 µm thick and has a porosity of 40%.

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**Problem 5.4**: Using Equation 5.10, calculate the limiting current density for a fuel cell cathode running on air at STP (Standard Temperature and Pressure). Assume only O₂ and N₂ are present and ignore the presence of water vapor. Assume that the diffusion layer is 500 μm thick and has a porosity of 40%.
Transcribed Image Text:**Problem 5.4**: Using Equation 5.10, calculate the limiting current density for a fuel cell cathode running on air at STP (Standard Temperature and Pressure). Assume only O₂ and N₂ are present and ignore the presence of water vapor. Assume that the diffusion layer is 500 μm thick and has a porosity of 40%.
### Equation 5.10

The equation shown is:

\[ j_L = nF D_{\text{eff}} \frac{c_R^0}{\delta} \]

#### Explanation of Terms:

- \( j_L \) is the limiting current density.
- \( n \) is the number of electrons involved in the reaction.
- \( F \) is Faraday's constant, representing the charge of one mole of electrons.
- \( D_{\text{eff}} \) is the effective diffusion coefficient.
- \( c_R^0 \) is the initial concentration of the reactant.
- \( \delta \) is the diffusion layer thickness.

This equation is often used in electrochemistry and relates the limiting current density to the diffusion of reactants in an electrochemical cell. The limiting current is determined by the rate at which the reactant can be supplied to the electrode surface, which is governed by factors like the diffusion coefficient and the concentration gradient.
Transcribed Image Text:### Equation 5.10 The equation shown is: \[ j_L = nF D_{\text{eff}} \frac{c_R^0}{\delta} \] #### Explanation of Terms: - \( j_L \) is the limiting current density. - \( n \) is the number of electrons involved in the reaction. - \( F \) is Faraday's constant, representing the charge of one mole of electrons. - \( D_{\text{eff}} \) is the effective diffusion coefficient. - \( c_R^0 \) is the initial concentration of the reactant. - \( \delta \) is the diffusion layer thickness. This equation is often used in electrochemistry and relates the limiting current density to the diffusion of reactants in an electrochemical cell. The limiting current is determined by the rate at which the reactant can be supplied to the electrode surface, which is governed by factors like the diffusion coefficient and the concentration gradient.
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