5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 160 140 120 100 80 60 40 20 3.4 10,000 20,000 30,000 Time (s) 10,000 30,000 20,000 Time (s) (a) (b) A Figure 14.7 Kinetic data for conversion of methyl isonitrile into acetonitrile. Pressure, CHgNC (torr) In pressure, CH3NC

Q: 43) which of the folowing orbitaldlstinations islare) not possible? a1s 6,2p C.2d d.4f

A: Orbitals are specific places in Orbits where Electron finding possibility is maximum. These are…

Q: Explain the basis of the VSEPR approach.

A: The basis of the VSEPR approach has to be explained.

Q: Calculate no of microstate in p³ configuration

A: There is tye mathematical formula from where we can calculator the no of microstates .

Q: Give chemical reaction in support of the statement that all the bonds inPCl5 molecule are not…

A: PCl5 molecule- In PCl5 molecule dsp3 hybridization is present. Molecular domain geometry is…

Q: (9) Energy and electron transfer processes in a supramolecular system A-L-B, where A is the light…

A: when molecule  A absorbs the light it got excited and give electron to B , B emits the light and act…

Q: The standard potential of a redox couple is a measure of the thermodynamic tendency of an atom, ion,…

A: Standard potential indicates the capacity/tendency of an aromatic hydrocarbon to accept an electron…

Q: Name one proof that hybridisation actually occurs.

A: A question based on hybridisation, which is to be accomplished.

Q: Sketch the frontier orbitals of N2 and CO molecules and highlight the differences between them

A: The electron occupation taking place at the HOMO and LUMO (highest-energy occupied and lowest-energy…

Q: Benzene has the following roots for the Huckel polynomial: x=-2, -1, -1, +1, +1, +2 a) Derive the…

A:

Q: Dipole moment m Polarizability volume a¢ HCl 1.08 D 2.63´10-30 m3 HI 0.42 D 5.45´10-30 m3…

A: The induced dipole moment of any molecule is given by  μ = αE  where E = electric field strength  α…

Q: Consider a N₂ molecule in its first excited electronic state, that is, when an electron in the…

A: To calculate the energy difference between the LUMO and HOMO of N2 given that an electron on…

Q: create and justify the molecular orbital diagram correlated from the lewis dot structure for iodine…

A:

Q: There is some indication that other hydrogen ring compounds and ions in addition to H3 and D3…

A: The Huckel determinant for each molecule is written as follows:

Q: Suppose that an ethene molecule is ionized by a photon to give the  C2 H+4 ion. Will the bond order…

A: Ethene molecule is CH2=CH2. Both the ‘C’ atoms in it are sp2 hybridized. It consists of 1 sigma bond…

Q: the quantam averbors (^,2 the follo ing Deler mine ,4pin) of A.) B 2) Li 3.) Hg 3.) Al

A:

Q: These are very weak interactions caused by the momentary changes in electron density in a molecule

A: "Van Der Waals" force or interaction is very well interaction caused by the momentary changes in…

Q: Mary, Molecules experience multiple types of inter Particle foreses, what is the name of the…

A: we have to determine the strongest interparticle forces present in the given molecules

Q: Evaluate the quotient.2.29×1047.63×10−6=

A: First multiplying the first two numbers of the given expression:

Q: Is it possible that azo dye is possible in water?

A: Presence of azo dyes in water

Q: Give the Lewis-structure of a molecule containing both a σp-p and a πp-p overlap of orbitals. Then…

A: given σp-p and πp-p overlap orbital we need to indicate the lweis structure σ and π bonds in the…

Q: Which of the molecules, CO2, NH3 and BCl3 will be polar?

A: Non polar compounds will have non polar bonds or polar bonds in which dipoles cancle each other.

Q: 9.25 Calculate the root-mean-square clei of 12C160 in the v librium bond length of 112.832 pm.…

A:

Q: Estimate the dipole moment of an HCl molecule from the electronegativities of the elements and…

A: Given molecule: HCl

Q: Write the va lence bond wavefunction of a P2 molecule. Why is P4 a stable form of molecular…

A:

Q: P10B.3 Consider the H,O molecule, which belongs to the group C, Take the molecule to lie in the…

A: Consider the H2O molecule, which belongs to the C2V point group. use of displacement coordinates…

Q: 1. Calculate the internal energy and heat capacity of the conduction electrons in a block of…

A: Given: volume of block, V=2 m3Temperature, T=600∘C = 600+273                            =873KAlso,…

Q: wich conjugate pir would be the best amortiguator а. НСI, NaCl ОБ. СНЗСООН, СНЗСООNa О с. НЗРО4,…

A: Given options are : a). HCl, NaCl b). CH3COOH, CH3COONa  c). H3PO4, Na3PO3  d). HNO3, NaNO3 e).…

Q: In CH2BrCl, are the hydrogen atoms equivalent (i.e., do they have identical environments with…

A: Given compound : CH2BrCl

Q: What is the role of wave interference in determining whether a molecular orbital is bonding or…

A: Molecular orbitals are formed by the linear combination of atomic orbitals

Q: Can atom have more than one ionization potentials?

A: Yes, I multi electron atoms have more than one ionisation potential values. For example Mn atom.

Q: 8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, W, = 0.200,H…

A: Given the HCl bonding orbital as, Where 0.20 and 0.98 are individual coefficients of normalisation…

Q: (A)Write the Hückel Hamiltonian matrix for benzene. (B)The pictures below represent a top view of…

A: The objective of the question is to write the Huckel Hamiltonian matrix for benzene and to arrange…

Q: Calculate AS°; for the following compounds in J mol1 K-1. C2H4(g) AS°f = i J mol 1 K1 HC2H3O2(1) AS°…

A: A) Given reaction is 2C(s, graphite) + 2H2(g) ----------> C2H4(g) ∆S°rxn = S° products - s°…

Q: 6. What is the linear density (fraction of the line length occupied by atoms) for the [1120]…

A:

Repulsive and Total Interactions Between Molecules

Intermolecular forces are the repulsive or attractive interaction between the molecules. Due to the coulomb’s law, there will be a coulomb force that exists between two or more charged species. If the charge of both molecules is positive or negative, then that will lead to repulsive forces. When they have opposite charges, then the force is attractive.