5. Synthesize the following product from the starting material given. Provide reagents and intermediate products for each step. a) OH Br b) OH HO
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- orgo chem questions4. from each. a) Predict the product of the following reactions. Provide the major organic product d) OH 1. TsCl, pyridine 2. H CO₂CH3 Na₂CO3 SH3) Draw the structures of the major organic product(s) for the following reactions. HI in CH₂Cl₂ 3 excess Cl₂ in H₂O H₂SO4 in H₂O (Two products) Br-Cl in THF 1) BH3 2) alkaline H₂O₂ OSO4 + HOOH
- 5. Consider the following reactions scheme below. NOH Step II OH Step 1 HCN A C8H5MGCI / H3O* B a) Write a possible structure for compounds A and B. b) Determine reagents that needed and state the conditions (if any) for step I and stepll. c) Give name of the reaction for step I.7. How would you complete the following syntheses? Provide the reagents and products of each step. OH OH ⇒e" a. b. d. H Et OMe5) Provide the products for reactions a) and b) below. Provide a mechanism for b) only. a) Br2 light b) CH3OH Br
- Which is the MAJOR product of the following reaction? Et 1) BH3:THF 2) H2O2, NaOH Which of the following best describes a key step in the mechanism for the reaction below? HO ... CH3 -CH3 dihydroxylation + en H3C- H3C- HO. electrophilic addition reaction to form a carbocation intermediate B nucleophilic attack by an alkene to form a cyclic (epoxide) intermediate elimination reaction by abstraction of a beta-hydrogen D free-radical substitution at the carbonyl carbon Which alkene will produce the HIGHEST yield of the alkyl halide below? Br. alkene HBr |Complete the following reactions by identifying the majority product(s) or the reaction conditions that are missing. No mechanism is neededHeck reactions take place with alkynes as well as alkenes. The following conversion involves an intramolecular Heck reaction followed by an intermolecular Heck. Work out the reaction sequence on a separate sheet of paper, and then draw the structure of the palladium-containing intermediate A. 1% mol Pd(OAc)₂2 CO₂Me 4% mol Ph P CH₂CN A (1 ring) C (2 rings) (2 rings) • Consider E/Z stereochemistry of alkenes. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Use R1 to represent the palladium complex. The R group tool is located in the charges and lone pairs drop-down menu. 0- ✪ Sn [F MeO₂C
- Predict the major organic product of the reaction. An alkene has one substituent, a tert butyl group. This reacts with H B r to give the product. Draw the major organic product.Provide the major organic product in the reaction shown below.Q17. Compound 1 can undergo an intramolecular reaction to give cyclic product 2. Using curly arrows, show the mechanism of this reaction – note that the mechanism involves more than one elemental step - and draw the structure of 2; chemical formula is provided as guidance. H2N. C5H9NO CH;OH 2