5. Synthesize the following product from the starting material given. Provide reagents and intermediate products for each step. a) OH Br b) OH HO
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- 4. from each. a) Predict the product of the following reactions. Provide the major organic product d) OH 1. TsCl, pyridine 2. H CO₂CH3 Na₂CO3 SHBicyclo-2,5-heptadiene can be prepared in two steps from cyclopentadiene and vinyl chloride. Provide a mechanism for each step.2. Provide a synthesis of the following ether starting from an alkene, ethanol, and any necessary reagents. CH3 CH3 H3C
- Finish the indicated reaction by filling in and starting materials, reagents or products as needed Show how to synthesize the following product as the major product starting with 2,2- dimethylpropane as the starting material. You may use additional reagents and any number of steps. Be sure to list each step with all reactants/reagents/conditions required. (Do not use hydrogenation reactions) from4) Synthesize the following molecule using the indicated starting material, showing all reagents used in each step. H. from CN H HO EtO
- 7. Provide the synthesis for the following product starting with the provide starting material. More than one step is required. Show the mechanism for each reaction. CI- Cl- Starting Material ProductStarting with benzene and using any other necessary reagents of your choice, create a synthesis (or sytheses) for each of the following compounds.Provide the necessary reagents to accomplish the desired organic reactions. Please number the steps and note that some reactions will require more than one step. Me Meo. Meo. CF MeO
- Br Brz CH3 CH3 H3C CH2CI2 H3C Br Electrophilic addition of bromine, Br2; to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl). In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br: :Br: .CH3 H3C H3C CH3 Br:Show how to synthesize the following product as the major product starting with 2,2-dimethylpropane as the starting material. You may use additional reagents and any number of steps. Be sure to list each step with all reactants/reagents/conditions required. (Do not use hydrogenation reactions). Write the process.Heck reactions take place with alkynes as well as alkenes. The following conversion involves an intramolecular Heck reaction followed by an intermolecular Heck. Work out the reaction sequence on a separate sheet of paper, and then draw the structure of the palladium-containing intermediate A. 1% mol Pd(OAc)₂2 CO₂Me 4% mol Ph P CH₂CN A (1 ring) C (2 rings) (2 rings) • Consider E/Z stereochemistry of alkenes. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Use R1 to represent the palladium complex. The R group tool is located in the charges and lone pairs drop-down menu. 0- ✪ Sn [F MeO₂C