5. Spectroscopic measurements indicate that the rotational constants of SO2, a non-linearmolecule, are 2.02736, 0.34417, and 0.29354 cm ¹. Note: ks = 0.69503476 cm-¹/K.Reference (NIST): https://cccbdb.nist.gov/expgeom2.asp?casno=7446095&charge=0(a) Compute Zrot at T = 385 K assuming its symmetry number is o= 2. Hint: Using therotational temperatures for the molecule might make this easier.(b) At what temperature would the partition function equal 2.4 x 104? LabelABсDEFGHJKLMNOPQRSTUVWXEquationEtotal= Eetec + Evib + Erot + EtransE₂ = hw (v + ²)Zvib =Evib =h²Erot= 27 J+1)=Bjj+1)Etrans (nx. ny. ₂) =3N-6[₁ hw; (v₁ + ²)3N-6(-1w(n)=-E-ENGE=N = n₁ZtransP₁ = gjeti/kgzταz=₁9₁e-B, or z=₁e-/kgh² (n.2B=8m L-Z=1 azz apZrotZrot =1kgT(9₁)",n₂!Zvib =■N!+A₁ e₁/ktgjet/katΣge-B(2mmk, T., 3/2h²Berot= ksz = Zelec Zvib Zrot ZtranskgTBaerib=a In Zaß√R T3, Ꮎ Ꮎ Ꮎe-Bho/21-e-BhuhokB2V+3N-6e-Bhoj/z=-ПIG-e-Bhay-Oyib./2T-e-vib/TZvibiP(b) = (1-e-b/T)e-/T

Answered: Image /qna-images/answer/76203ac4-1814-415a-bacd-f161bdcf3a08.jpg

5. Spectroscopic measurements indicate that the rotational constants of SO2, a non-linear molecule, are 2.02736, 0.34417, and 0.29354 cm ¹. Note: ks = 0.69503476 cm-¹/K. Reference (NIST): https://cccbdb.nist.gov/expgeom2.asp?casno=7446095&charge=0 (a) Compute Zrot at T = 385 K assuming its symmetry number is o= 2. Hint: Using the rotational temperatures for the molecule might make this easier. (b) At what temperature would the partition function equal 2.4 × 104?

5. Spectroscopic measurements indicate that the rotational constants of SO2, a non-linear molecule, are 2.02736, 0.34417, and 0.29354 cm ¹. Note: ks = 0.69503476 cm-¹/K. Reference (NIST): https://cccbdb.nist.gov/expgeom2.asp?casno=7446095&charge=0 (a) Compute Zrot at T = 385 K assuming its symmetry number is o= 2. Hint: Using the rotational temperatures for the molecule might make this easier. (b) At what temperature would the partition function equal 2.4 × 104?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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