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5. For the following sequence of reactions, propose electron curved arrows: H N H"N H-N EN H + e. HÖ'N + POH + H N ОН (draw next step using this resonance structure) H ON-N H H,0 нн + + H H NEN

5. For the following sequence of reactions, propose electron curved arrows: H N H"N H-N EN H + e. HÖ'N + POH + H N ОН (draw next step using this resonance structure) H ON-N H H,0 нн + + H H NEN

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Reaction Sequence Analysis with Electron Curved Arrows #### Sequence of Reactions **Initial Reaction:** 1. A compound with a nitrogen-nitrogen double bond and an adjacent nitrogen with a hydrogen bond is reacted with a hydroxide ion (\(OH^-\)). **Intermediate Steps:** 2. This leads to a resonance structure where the nitrogen double bond shifts, and the hydroxide ion interacts with the nitrogen. 3. The resonance form stabilizes with a neutral \(\text{H}_2\text{O}\) and a deprotonated nitrogen. **Subsequent Reactions:** 4. The resonance structure then reacts with additional water (\(\text{H}_2\text{O}\)). 5. The sequence progresses through various electron shift stages, indicated by curved arrows, showing electron pair movements. **Final Products:** 6. This series of shifts ultimately leads to the formation of an alkane (\(\text{H}_3\text{C}-\text{CH}_3\)) and nitrogen gas (\(\text{N}_2\)). #### Explanation of Electron Movement - **Curved Arrows**: Indicate the movement of electron pairs. These arrows are crucial for showing how electrons are transferred between different orbitals during reactions. - **Resonance Structures**: Highlight the different possible distributions of electron density within the molecule, enhancing understanding of molecular stability and reactivity. #### Key Concepts - **Resonance**: Provides multiple structural forms a molecule can take, sharing electrons differently to achieve stability. - **Electron Pair Movement**: Vital for understanding reactions, showing changes in bonding and formation of intermediates. This exercise illustrates the importance of resonance and electron flow in understanding complex chemical reactions, crucial in fields like organic chemistry and biochemistry.
Transcribed Image Text:### Reaction Sequence Analysis with Electron Curved Arrows #### Sequence of Reactions **Initial Reaction:** 1. A compound with a nitrogen-nitrogen double bond and an adjacent nitrogen with a hydrogen bond is reacted with a hydroxide ion (\(OH^-\)). **Intermediate Steps:** 2. This leads to a resonance structure where the nitrogen double bond shifts, and the hydroxide ion interacts with the nitrogen. 3. The resonance form stabilizes with a neutral \(\text{H}_2\text{O}\) and a deprotonated nitrogen. **Subsequent Reactions:** 4. The resonance structure then reacts with additional water (\(\text{H}_2\text{O}\)). 5. The sequence progresses through various electron shift stages, indicated by curved arrows, showing electron pair movements. **Final Products:** 6. This series of shifts ultimately leads to the formation of an alkane (\(\text{H}_3\text{C}-\text{CH}_3\)) and nitrogen gas (\(\text{N}_2\)). #### Explanation of Electron Movement - **Curved Arrows**: Indicate the movement of electron pairs. These arrows are crucial for showing how electrons are transferred between different orbitals during reactions. - **Resonance Structures**: Highlight the different possible distributions of electron density within the molecule, enhancing understanding of molecular stability and reactivity. #### Key Concepts - **Resonance**: Provides multiple structural forms a molecule can take, sharing electrons differently to achieve stability. - **Electron Pair Movement**: Vital for understanding reactions, showing changes in bonding and formation of intermediates. This exercise illustrates the importance of resonance and electron flow in understanding complex chemical reactions, crucial in fields like organic chemistry and biochemistry.
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