5. (18 pts: 6 pts each) For a reaction: N2O4 (g) 2 NO2 (g), the thermodynamic constants at 25°C are listed in the table below: Compound NO2 (g) AH (kJ/mol) AG+ (kJ/mol) So (J/mol·K) 33.20 51.30 240 N2O4 (g) 9.16 97.82 304.2 (a) What is the equilibrium constant K of this reaction at 25°C? (b) In a closed container, the partial pressures of N2O4 (g) and NO2 (g) initially are 0.10 atm and 0.10 atm, respectively. Is this reaction spontaneous (i.e. moving forward) at 25°C? (c) Continued from (b), what will be the partial pressures of N2O4 and NO2 when the system reaches equilibrium? (Help: Root of a quadratic equation is in Supporting Table-1.)

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5. (18 pts: 6 pts each) For a reaction:
N2O4 (g) 2 NO2 (g), the thermodynamic
constants at 25°C are listed in the table below:
Compound
NO2 (g)
AH (kJ/mol)
AG+ (kJ/mol)
So (J/mol·K)
33.20
51.30
240
N2O4 (g)
9.16
97.82
304.2
(a) What is the equilibrium constant K of this reaction at 25°C?
(b) In a closed container, the partial pressures of N2O4 (g) and NO2 (g) initially are 0.10 atm
and 0.10 atm, respectively. Is this reaction spontaneous (i.e. moving forward) at 25°C?
(c) Continued from (b), what will be the partial pressures of N2O4 and NO2 when the system
reaches equilibrium? (Help: Root of a quadratic equation is in Supporting Table-1.)
Transcribed Image Text:5. (18 pts: 6 pts each) For a reaction: N2O4 (g) 2 NO2 (g), the thermodynamic constants at 25°C are listed in the table below: Compound NO2 (g) AH (kJ/mol) AG+ (kJ/mol) So (J/mol·K) 33.20 51.30 240 N2O4 (g) 9.16 97.82 304.2 (a) What is the equilibrium constant K of this reaction at 25°C? (b) In a closed container, the partial pressures of N2O4 (g) and NO2 (g) initially are 0.10 atm and 0.10 atm, respectively. Is this reaction spontaneous (i.e. moving forward) at 25°C? (c) Continued from (b), what will be the partial pressures of N2O4 and NO2 when the system reaches equilibrium? (Help: Root of a quadratic equation is in Supporting Table-1.)
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