5. (18 pts: 6 pts each) For a reaction: N2O4 (g) 2 NO2 (g), the thermodynamic constants at 25°C are listed in the table below: Compound NO2 (g) AH (kJ/mol) AG+ (kJ/mol) So (J/mol·K) 33.20 51.30 240 N2O4 (g) 9.16 97.82 304.2 (a) What is the equilibrium constant K of this reaction at 25°C? (b) In a closed container, the partial pressures of N2O4 (g) and NO2 (g) initially are 0.10 atm and 0.10 atm, respectively. Is this reaction spontaneous (i.e. moving forward) at 25°C? (c) Continued from (b), what will be the partial pressures of N2O4 and NO2 when the system reaches equilibrium? (Help: Root of a quadratic equation is in Supporting Table-1.)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
5. (18 pts: 6 pts each) For a reaction:
N2O4 (g) 2 NO2 (g), the thermodynamic
constants at 25°C are listed in the table below:
Compound
NO2 (g)
AH (kJ/mol)
AG+ (kJ/mol)
So (J/mol·K)
33.20
51.30
240
N2O4 (g)
9.16
97.82
304.2
(a) What is the equilibrium constant K of this reaction at 25°C?
(b) In a closed container, the partial pressures of N2O4 (g) and NO2 (g) initially are 0.10 atm
and 0.10 atm, respectively. Is this reaction spontaneous (i.e. moving forward) at 25°C?
(c) Continued from (b), what will be the partial pressures of N2O4 and NO2 when the system
reaches equilibrium? (Help: Root of a quadratic equation is in Supporting Table-1.)
Transcribed Image Text:5. (18 pts: 6 pts each) For a reaction: N2O4 (g) 2 NO2 (g), the thermodynamic constants at 25°C are listed in the table below: Compound NO2 (g) AH (kJ/mol) AG+ (kJ/mol) So (J/mol·K) 33.20 51.30 240 N2O4 (g) 9.16 97.82 304.2 (a) What is the equilibrium constant K of this reaction at 25°C? (b) In a closed container, the partial pressures of N2O4 (g) and NO2 (g) initially are 0.10 atm and 0.10 atm, respectively. Is this reaction spontaneous (i.e. moving forward) at 25°C? (c) Continued from (b), what will be the partial pressures of N2O4 and NO2 when the system reaches equilibrium? (Help: Root of a quadratic equation is in Supporting Table-1.)
Expert Solution
steps

Step by step

Solved in 2 steps

Blurred answer
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY