Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The graph above is an IR (Infrared) spectrum that displays various absorption bands which correspond to different vibrational modes of the molecular bonds within the compound being examined. Here is a detailed breakdown of the key absorption bands and their corresponding wavenumbers:
- **3044 cm⁻¹:** Indicates the presence of aromatic C-H stretching.
- **2923 cm⁻¹:** Corresponds to aliphatic C-H stretching vibrations.
- **2734 cm⁻¹:** This peak is characteristic of aldehyde C-H stretching, which helps to distinguish between aldehydes and ketones, the latter of which typically do not show this absorption band.
- **1704 cm⁻¹:** Indicates the presence of C=O (carbonyl) stretching vibration, which is common in both aldehydes and ketones.
- **1608 cm⁻¹:** Typically associated with aromatic ring stretching, indicating an aryl (aromatic) group in the compound.
- **1450 cm⁻¹ and 1388 cm⁻¹:** These bands are due to C-H bending vibrations.
- **810 cm⁻¹:** Often associated with out-of-plane bending vibrations of aromatic C-H bonds.
Based on the presence of the absorption band at 2734 cm⁻¹, it suggests that the compound is more likely an aldehyde rather than a ketone.
**Additionally, is this compound “aryl”, “alkyl”, or both? ______**
Considering the presence of bands at 3044 cm⁻¹ and 1608 cm⁻¹, which are indicative of aromatic C-H stretching and aromatic ring stretching respectively, this compound contains an aryl (aromatic) group. The absorption bands at 2923 cm⁻¹ and 1450 cm⁻¹/1388 cm⁻¹ point towards the presence of alkyl C-H stretching and bending. Hence, the compound contains both aryl and alkyl groups.
### Conclusion
- **Type of Compound:** Aldehyde
- **Nature of Groups Present:** Both aryl and alkyl groups](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F053a7dd4-6035-4ca1-b497-47ec6b123526%2F145275c3-d5dc-40a3-8ee4-1ac5f1acdfb5%2Fc0grmh9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Infrared (IR) Spectroscopy Analysis
**4.** The following IR spectrum comes from either an aldehyde or a ketone. Which is it? ______

The graph above is an IR (Infrared) spectrum that displays various absorption bands which correspond to different vibrational modes of the molecular bonds within the compound being examined. Here is a detailed breakdown of the key absorption bands and their corresponding wavenumbers:
- **3044 cm⁻¹:** Indicates the presence of aromatic C-H stretching.
- **2923 cm⁻¹:** Corresponds to aliphatic C-H stretching vibrations.
- **2734 cm⁻¹:** This peak is characteristic of aldehyde C-H stretching, which helps to distinguish between aldehydes and ketones, the latter of which typically do not show this absorption band.
- **1704 cm⁻¹:** Indicates the presence of C=O (carbonyl) stretching vibration, which is common in both aldehydes and ketones.
- **1608 cm⁻¹:** Typically associated with aromatic ring stretching, indicating an aryl (aromatic) group in the compound.
- **1450 cm⁻¹ and 1388 cm⁻¹:** These bands are due to C-H bending vibrations.
- **810 cm⁻¹:** Often associated with out-of-plane bending vibrations of aromatic C-H bonds.
Based on the presence of the absorption band at 2734 cm⁻¹, it suggests that the compound is more likely an aldehyde rather than a ketone.
**Additionally, is this compound “aryl”, “alkyl”, or both? ______**
Considering the presence of bands at 3044 cm⁻¹ and 1608 cm⁻¹, which are indicative of aromatic C-H stretching and aromatic ring stretching respectively, this compound contains an aryl (aromatic) group. The absorption bands at 2923 cm⁻¹ and 1450 cm⁻¹/1388 cm⁻¹ point towards the presence of alkyl C-H stretching and bending. Hence, the compound contains both aryl and alkyl groups.
### Conclusion
- **Type of Compound:** Aldehyde
- **Nature of Groups Present:** Both aryl and alkyl groups
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