Please correct answer and don't use hand rating 4. Nominally pure water in the laboratory generally contains dissolved CO2, in itshydrated form: H2CO3(aq), which ionizes in accord with:K₁ = 4.47 x 10-7 M and1) H2CO3 HCO3 + H+K2 4.68 x 10-11 M2) HCO3 CO₂²- + H+The pH is measured to be 5.5. The contribution of the ionization of water itselfto the H+ ion concentration may be neglected. Evaluate the equilibriummolarities of the species H*, H2CO3, HCO3 and CO2²-.

We are given two dissociation constants:K1=4.47×10−7K2=4.68×10−11 The concentration of [H+]:Since pH…

Answered: 4. Nominally pure water in the…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter15: Acid–base Equilibria

Section: Chapter Questions

Problem 107AP

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Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?
Given three acid-base indicatorsâ€”methyl orange (end point at pH 4), bromthymol blue (end point at pH 7), and phenolphthalein (end point at pH 9)â€”which would you select for the following acid-base titrations? (a) perchloric acid with an aqueous solution of ammonia (b) nitrous acid with lithium hydroxide (c) hydrobromic acid with strontium hydroxide (d) sodium fluoride with nitric acid
Marble is almost pure CaCO3. Acid rain has a devastating effect on marble statuary left outdoors. Assume that the reaction which occurs is CoCO3(s)+ H+(aq)Ca2+(aq)+HCO3(aq) Neglecting all other competing equilibria and using Tables 15.1 and 13.2, calculate (a) K for the reaction. (b) the molar solubility of CaCO3 in pure water. (c) the molar solubility of CaCO3 in acid rainwater with a pH of 4.00.
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If you wanted to buffer a solution at pH = 4.00 or pH = 10.00, how would you decide which weak acidconjugate base or weak baseconjugate acid pair to use? The second characteristic of a good buffer is good buffering capacity. What is the capacity of a buffer? How do the following buffers differ in capacity? How do they differ in pH? 0.01 M acetic acid/0.01 M sodium acetate 0.1 M acetic acid/0.1 M sodium acetate 1.0 M acetic acid/1.0 M sodium acetate
The simplest amino acid is glycine, H2NCH2CO2H. The common feature of amino acids is that they contain the functional groups: an amine group, -NH2, and a carboxylic acid group, -CO2H. An amino acid can function as either an acid or a base. For glycine, the acid strength of the carboxyl group is about the same as that of acetic acid. CH3CO2H, and the base strength of the amino group is slightly greater than that of ammonia, NH3. (a) Write the Lewis structures of the ions that form when glycine is dissolved in 1 M HCl and in 1 M KOH. (b) Write the Lewis structure of glycine when this amino acid is dissolved in water. (Hint: Consider the relative base strengths of the -NH2 and -CO2- groups.)
You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.
In a titration, the equivalence point is the moment at which the number of moles of H+ from the acid that has been added is equal to the number of moles of OH- from the base that has been added. Remember that in a molecule like H2SO4, there are 2 moles of H+ per mole of H2SO4. 18.63 mL of 0.100M H2SO4(aq) is placed in a beaker. After 16.42 mL of NaOH is added to the beaker, the equivalence point is reached. What is the concentration (M) of the NaOH solution? Report your answer with 3 sig figs
The acid-base indicator "Thymol Blue" has two transition ranges as listed below (with the corresponding acid dissociation constants): 7. Ka AcidColour BaseColour Thymol Blue 1 Thymol Blue 2 2.24 x 102 Red Yellow 1.26 x 10 Yellow Blue What colour would you expect it to be at the following pH values? Briefly justify your answers. (a) (b) (c) (d) 0.9 5.2 7.8 10.7
In a titration, the equivalence point is the moment at which the number of moles of H+ from the acid that has been added is equal to the number of moles of OH- from the base that has been added. Remember that in a molecule like H2SO4, there are 2 moles of H+ per mole of H2SO4. 16.75 mL of 0.100M H2SO4(aq) is placed in a beaker. After 17.65 mL of NaOH is added to the beaker, the equivalence point is reached. What is the concentration (M) of the NaOH solution?

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