4. For each of the pairs of molecules drawn below, place letters in the corner boxes corresponding to all accurate descriptions of the relationship between the two molecules. a) b) c) d) H3C HO НО. HO Br OH Br H H HH HH CH3 но. Br Br- HO OH HH HH CH3 O CH3 OH all letters that apply all letters that apply all letters that apply all letters that apply A enantiomers B diasteromers C different conformations of the same molecule D identical comformations of the same molecule E constitutional isomers F stereoisomers G different molecules H both are chiral I neither is chiral

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**Problem 4:** For each of the pairs of molecules drawn below, place letters in the corner boxes corresponding to all accurate descriptions of the relationship between the two molecules.

**Options:**
- A: enantiomers
- B: diastereomers
- C: different conformations of the same molecule
- D: identical conformations of the same molecule
- E: constitutional isomers
- F: stereoisomers
- G: different molecules
- H: both are chiral
- I: neither is chiral

**Pairs of Molecules:**

**a)**
- Two cyclohexane rings, each with an OH and a Br group.
- Evaluate their stereochemistry to determine the relationship.

**b)**
- First molecule: A cyclopropane with an OH and Br on adjacent carbons, along with two additional hydrogens and a methyl group.
- Second molecule: Linear chain with an OH and Br on adjacent carbons.
- Assess isomer type and connectivity to find the correct descriptors.

**c)**
- Two ring structures with similar substituents: HO, CH₃O, and CH₃.  
- Compare the orientation and configuration of substituents.

**d)**
- Two cyclohexane-like rings with multiple hydrogen atoms. One has an OH group in the equatorial position, while the other appears in a similar position but might have different spatial orientation due to stereochemistry.

For each pair, analyze the spatial arrangement and use the provided options to describe the relationships accurately.
Transcribed Image Text:**Problem 4:** For each of the pairs of molecules drawn below, place letters in the corner boxes corresponding to all accurate descriptions of the relationship between the two molecules. **Options:** - A: enantiomers - B: diastereomers - C: different conformations of the same molecule - D: identical conformations of the same molecule - E: constitutional isomers - F: stereoisomers - G: different molecules - H: both are chiral - I: neither is chiral **Pairs of Molecules:** **a)** - Two cyclohexane rings, each with an OH and a Br group. - Evaluate their stereochemistry to determine the relationship. **b)** - First molecule: A cyclopropane with an OH and Br on adjacent carbons, along with two additional hydrogens and a methyl group. - Second molecule: Linear chain with an OH and Br on adjacent carbons. - Assess isomer type and connectivity to find the correct descriptors. **c)** - Two ring structures with similar substituents: HO, CH₃O, and CH₃. - Compare the orientation and configuration of substituents. **d)** - Two cyclohexane-like rings with multiple hydrogen atoms. One has an OH group in the equatorial position, while the other appears in a similar position but might have different spatial orientation due to stereochemistry. For each pair, analyze the spatial arrangement and use the provided options to describe the relationships accurately.
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