Please correct answer and don't used hand raiting 4) Compound A, C5H10, absorbs one molar equivalent of H2 reaction upon reaction with excess H2/Pd/C. Uponreaction with ozone followed by aqueous acidic zinc, two separate molecules are formed, one aldehyde and oneketone. a. How many alkenes does A contain? How many rings? b. What must be the structure of A?

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Answered: 4) Compound A, C5H10, absorbs one molar…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.SE: Something Extra

Problem 29VC

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a. What alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2? b. What alkane, with molecular formula C7H16, forms seven monochlorinated products (disregarding stereoisomers) when heated with Cl2?
7) You want to synthesize 3-methyl-2-pentene from 2-chloro-3-methylpentane. Which reagent would you use? a. HCI, heat b. NH:(aq), 25°C c. CH:CO2NA, CH:CO2H, heat d. CH3CH2ONA, CH3CH2OH, heat e. CН:CH2ОН, heat
a. Draw the structures and give the common and systematic names for alkynes with molecular formula C7H12. Ignore stereosiomers. (Hint: There are 14.) b. How many would there be if stereoisomers are included?
1. Reaction of 2,3-dimethyl-1-butene with HBr leads to an alkyl bromide, C6H13Br. On treatment of this alkyl halide with KOH in methanol, elimination of HBr occurs and a hydrocarbon that is isometric with the starting alkene is formed. What is the structure of this hydrocarbon and how do you think it is formed from an alkyl bromide? 2. 1-Octen-3-ol is a potent mosquito attractant commonly used in mosquito traps. A number of reactions, including hydrogenation, will transform 1-Octen-3-ol into a less effective molecule. Write a complete reaction equation for the hydrogenation of this alkenol.
2. Name each alkyne. a. CH3CH₂CH₂C=CH b. CH3CH₂CH₂C=CCH3 3. Predict the product of the following reactions. a. CH = CCH3 + HCI b. CH CCH₂CH3 + O2
Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent.a. HClb. CH3COClc. (CH3CO)2Od. excess CH3Ie. (CH3)2C = Of. CH3COCl, AlCl3g. CH3CO2Hh. NaNO2, HCli. Part (b), then CH3COCl, AlCl3j. CH3CHO, NaBH3CN
4. Syn and anti addition can occur with alkenes. 1. Describe syn and anti addition. b. Give an example of syn addition to an alkene and explain why it is syn. c. Give an example of anti addition to an alkene and explain why it is anti. 5. The following reactions shows the dehydration of 2-methylcyclohexanol. Why is 1-methylcyclohexene the major product? X OH H3PO4 84% 16%
Reagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
a. The following compounds have the same molecular formula as benzene. How many monobrominated products could each form? 1. HC‚CC‚CCH2CH3 2. CH2“CHC‚CCH“CH2 b. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.) c. How many dibrominated products could each of the compounds form if stereoisomers are included?
5. Which of these two compounds has a higher boiling point? Cyclopentanol The phenomenon responsible for that compound's higher boiling point is: cyclohexane 6. The electrophile in this reaction is: CH3CI benzene AICI3 a) CI* b) Cr c) CH,E- d) CH3*
Draw the structural formula for the product formed upon hydroboration/oxidation of the Alkene below.
4. Draw structural formulas for all possible monohalogenation products that might be formed in the following reactions, then assign them IUPAC names. (a) + Cl₂ light

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