3A. Below are GC results from the two reactions described in the experiment. In each reaction, an alcohol (n-butanol or t-butanol) is reacted with a 1:1 molar ratio of chloride and bromide and the ratio of products is analyzed to determine the rate law and reaction mechanism by which the reaction proceeds. Use the GC results below to determine what mechanism reaction 1 and reaction 2 proceed by and write a brief analysis of why you came to this conclusion. What alcohol is the starting material for each reaction? What is the rate law for each reaction? (It is important that you look up the boiling points of the four products of these two reactions to determine which is the chloro and which is the bromo product in each GC chromatogram. Assume that the peaks are eluted from the GC in order of boiling point.) Intensity (PA) Intensity (PA) 500000 400000 300000 200000 100000 0 -100000 250000 200000 150000 100000 50000 0 -50000 0.5 1 2 1 1 2 Reaction 1 Peak Number Retention Time (min) Peak Area %) 3.899 4.912 Reaction 1 1.5 3 Time (min) 1 2 Reaction 2 4 2.5 2 Time (min) 3 32.358 67.642 3.5 Reaction 2 Peak Number Retention Time (min) Peak Area %) 2.231 51.126 3.428 48.874 5 4 6 4.5
3A. Below are GC results from the two reactions described in the experiment. In each reaction, an alcohol (n-butanol or t-butanol) is reacted with a 1:1 molar ratio of chloride and bromide and the ratio of products is analyzed to determine the rate law and reaction mechanism by which the reaction proceeds. Use the GC results below to determine what mechanism reaction 1 and reaction 2 proceed by and write a brief analysis of why you came to this conclusion. What alcohol is the starting material for each reaction? What is the rate law for each reaction? (It is important that you look up the boiling points of the four products of these two reactions to determine which is the chloro and which is the bromo product in each GC chromatogram. Assume that the peaks are eluted from the GC in order of boiling point.) Intensity (PA) Intensity (PA) 500000 400000 300000 200000 100000 0 -100000 250000 200000 150000 100000 50000 0 -50000 0.5 1 2 1 1 2 Reaction 1 Peak Number Retention Time (min) Peak Area %) 3.899 4.912 Reaction 1 1.5 3 Time (min) 1 2 Reaction 2 4 2.5 2 Time (min) 3 32.358 67.642 3.5 Reaction 2 Peak Number Retention Time (min) Peak Area %) 2.231 51.126 3.428 48.874 5 4 6 4.5
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:3A. Below are GC results from the two reactions described in the experiment. In each reaction, an alcohol
(n-butanol or t-butanol) is reacted with a 1:1 molar ratio of chloride and bromide and the ratio of products
is analyzed to determine the rate law and reaction mechanism by which the reaction proceeds. Use the
GC results below to determine what mechanism reaction 1 and reaction 2 proceed by and write a brief
analysis of why you came to this conclusion. What alcohol is the starting material for each reaction? What
is the rate law for each reaction? (It is important that you look up the boiling points of the four products
of these two reactions to determine which is the chloro, and which is the bromo product in each GC
chromatogram. Assume that the peaks are eluted from the GC in order of boiling point.)
Intensity (PA)
Intensity (PA)
500000
400000
300000
200000
100000
0
-100000
250000
200000
150000
100000
50000
0
-50000
0.5
1
2
1
1
2
Reaction 1
Peak Number Retention Time (min) Peak Area %)
3.899
4.912
Reaction 1
1.5
3
Time (min)
1
2
Reaction 2
4
2
2.5
Time (min)
3
32.358
67.642
3.5
Reaction 2
Peak Number Retention Time (min) Peak Area %)
2.231
3.428
51.126
48.874
5
4
6
4.5
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