Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Question 35:**
Calculate the equilibrium constant at 25°C using standard cell potential data for the reaction:
\[ \text{Sn}(s) + \text{CuSO}_4(aq) \rightleftharpoons \text{Cu}(s) + \text{SnSO}_4(aq) \]
**Explanation:**
This problem involves using standard electrode potentials to determine the equilibrium constant for a given redox reaction at 25°C. The reaction involves solid tin (Sn) reacting with aqueous copper(II) sulfate (CuSO₄) to produce solid copper (Cu) and aqueous tin(II) sulfate (SnSO₄). To solve, you'll need to:
1. Identify the standard electrode potentials for both the oxidation and reduction reactions.
2. Use the Nernst equation to relate the standard cell potential to the equilibrium constant.
3. Calculate the equilibrium constant using the above data.
This exercise integrates concepts from electrochemistry and equilibrium chemistry.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Feb5e8bd6-22f0-449e-ab65-4b5e314c8967%2Fcb324cd7-f6d0-4421-b2fa-7726eb89a837%2F10mpi2d_processed.png&w=3840&q=75)
Transcribed Image Text:**Question 35:**
Calculate the equilibrium constant at 25°C using standard cell potential data for the reaction:
\[ \text{Sn}(s) + \text{CuSO}_4(aq) \rightleftharpoons \text{Cu}(s) + \text{SnSO}_4(aq) \]
**Explanation:**
This problem involves using standard electrode potentials to determine the equilibrium constant for a given redox reaction at 25°C. The reaction involves solid tin (Sn) reacting with aqueous copper(II) sulfate (CuSO₄) to produce solid copper (Cu) and aqueous tin(II) sulfate (SnSO₄). To solve, you'll need to:
1. Identify the standard electrode potentials for both the oxidation and reduction reactions.
2. Use the Nernst equation to relate the standard cell potential to the equilibrium constant.
3. Calculate the equilibrium constant using the above data.
This exercise integrates concepts from electrochemistry and equilibrium chemistry.
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