32. Refer to the attached photo. Appendix B Selected Thermodynamic ValuesAH; (298.15 K)(kd/mol)5 (298.15 K)OK mol)AG (298.15 K)(k3/mol)SpeciesCalciumCa(s)41.42Ca(g)178.2158.884144.3Ca?+(g)1925.9Ca+ (aq)542.8353.1-553.58CaC,(s)59.869.96-64.9CaCO,(s, calcite)-1206.9292.9-1128.79CaCl,(s)-795.8104.6-748.1CaF,(s)-1219.668.871167.3CaH,(s)-186.242-147.2CaO(s)-635.0939.75604.03CaS(s)-482.456.5477.4Ca(OH),(s)986.0983.39-898.49Ca(OH),(aq)-1002.82-74.5-868.07CaSo,(s)-1434.11106.7-1321.79CarbonC(s, graphite)C(s, diamond)5.740.1.8952.3772.9C(g)716.682158.096671.257,(CCIA(Cי-135.44216.4-65.21-102.9309.85-60.59CCl,(g)CHCI,()-134.47201.7-73.66295.71-70.34CHCI, (g)-103.14CH, (g, methane)-74.81186.264-50.72C,H, (g, ethyne)226.73200.94209.2C,H, (g, ethene)52.26219.5668.15C,H, (g, ethane)-84.68229.6-32.82269.9-23.49C,H3 (g, propane)C,Ho (g, butane)CH(C, benzene)-103.8-126.148310.227-16.98549.03172.8124.5CH14(e, hexane)296.0184.035198.78216.718CaH18 (g, octane)CHjg(C, octane)CH,OH(E, methanol)-208.447466.835-249.952361.2056.707-238.66126.8-166.27CH,OH(g, methanol)-200.66239.81-161.96CH;OH(aq, methanol)-245.931133.1175.31C,H,OH(C, ethanol)-277.69160.7-174.78CH,OH(g, ethanol)-235.1282.7-168.49C,H,OH(aq, ethanol)-288.3148.5-181.64 32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such asgaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unlessthere is some energy transfer from outside. This problem examines the feasibility of other reactions using coal andwater.a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C,H,(g), propanegas, C3H3(g), and liquid methanol, CH;OH(), with carbon dioxide as a by-product.b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any ofthem would be a feasible way to make the stated products.

a) the Balanced reaction are 1. 2C(s) + 3H2(g) → C2H6(g) 2. 3C(s) + 4H2(g) → C3H8(g)…

32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such as gaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unless there is some energy transfer from outside. This problem examines the feasibility of other reactions using coal and water. a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C2H(g), propane gas, C,Hs(g), and liquid methanol, CH;OH((), with carbon dioxide as a by-product. b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any of them would be a feasible way to make the stated products.

32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such as gaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unless there is some energy transfer from outside. This problem examines the feasibility of other reactions using coal and water. a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C2H(g), propane gas, C,Hs(g), and liquid methanol, CH;OH((), with carbon dioxide as a by-product. b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any of them would be a feasible way to make the stated products.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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32. Refer to the attached photo.

Appendix B Selected Thermodynamic Values
AH; (298.15 K)
(kd/mol)
5 (298.15 K)
OK mol)
AG (298.15 K)
(k3/mol)
Species
Calcium
Ca(s)
41.42
Ca(g)
178.2
158.884
144.3
Ca?+(g)
1925.9
Ca+ (aq)
542.83
53.1
-553.58
CaC,(s)
59.8
69.96
-64.9
CaCO,(s, calcite)
-1206.92
92.9
-1128.79
CaCl,(s)
-795.8
104.6
-748.1
CaF,(s)
-1219.6
68.87
1167.3
CaH,(s)
-186.2
42
-147.2
CaO(s)
-635.09
39.75
604.03
CaS(s)
-482.4
56.5
477.4
Ca(OH),(s)
986.09
83.39
-898.49
Ca(OH),(aq)
-1002.82
-74.5
-868.07
CaSo,(s)
-1434.11
106.7
-1321.79
Carbon
C(s, graphite)
C(s, diamond)
5.74
0.
1.895
2.377
2.9
C(g)
716.682
158.096
671.257
,(CCIA(Cי
-135.44
216.4
-65.21
-102.9
309.85
-60.59
CCl,(g)
CHCI,()
-134.47
201.7
-73.66
295.71
-70.34
CHCI, (g)
-103.14
CH, (g, methane)
-74.81
186.264
-50.72
C,H, (g, ethyne)
226.73
200.94
209.2
C,H, (g, ethene)
52.26
219.56
68.15
C,H, (g, ethane)
-84.68
229.6
-32.82
269.9
-23.49
C,H3 (g, propane)
C,Ho (g, butane)
CH(C, benzene)
-103.8
-126.148
310.227
-16.985
49.03
172.8
124.5
CH14(e, hexane)
296.018
4.035
198.782
16.718
CaH18 (g, octane)
CHjg(C, octane)
CH,OH(E, methanol)
-208.447
466.835
-249.952
361.205
6.707
-238.66
126.8
-166.27
CH,OH(g, methanol)
-200.66
239.81
-161.96
CH;OH(aq, methanol)
-245.931
133.1
175.31
C,H,OH(C, ethanol)
-277.69
160.7
-174.78
CH,OH(g, ethanol)
-235.1
282.7
-168.49
C,H,OH(aq, ethanol)
-288.3
148.5
-181.64

32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such as
gaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unless
there is some energy transfer from outside. This problem examines the feasibility of other reactions using coal and
water.
a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C,H,(g), propane
gas, C3H3(g), and liquid methanol, CH;OH(), with carbon dioxide as a by-product.
b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any of
them would be a feasible way to make the stated products.

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