3.46. Calculate Z and V for sulfur hexafluoride at 75°℃_and_15_bar by the followingequations:(a) The truncated virial equation [Eq. (3.38)] with the following experimental valuesof virial coefficients:B = −194 cm³.mol-1 C= 15,300 cm 6.mol-²(b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalizedPitzer correlation [Eqs. (3.58)-(3.62)] PVRTZ=-=B C1+ +VV²PVZ= =1+RTB=BP cRTCBO=0.083(3.58)0.422T1.6rBPRTB=B⁰+wB¹ (3.59)(3.61) B¹ = 0.139 -0.172T4.2r(3.38)(3.36)(3.62)

"Since you have asked multiple questions, we will solve the first question for you. If you want any…

3.46. Calculate Z and V for sulfur hexafluoride at 75°C and 15 bar by the following equations: (a) The truncated virial equation [Eq. (3.38)] with the following experimental values of virial coefficients: B = −194 cm³.mol-1 C= 15,300 cm6.mol-²

3.46. Calculate Z and V for sulfur hexafluoride at 75°C and 15 bar by the following equations: (a) The truncated virial equation [Eq. (3.38)] with the following experimental values of virial coefficients: B = −194 cm³.mol-1 C= 15,300 cm6.mol-²

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: dehydration

A: The mechanism of the dehydration reaction involves the initial protonation of the alcohol by a…

Q: The relationship Cp - Cy = a?TV holds for any substance in the gaseous, liquid, or solid state. = ,…

Q: 3. For a van der Waals gas, m show that Z= a V-b RTV, m m 1 (b) Using the Taylor series -≈…

Q: Suppose that 8.59 moles of A at 4.63 atm and 298.15 K and 5.68 moles of B at 5.83 atm and 298.15 K…

A: Given: For gas A Moles (nA) = 8.59 mol Pressure (PA) = 4.63 atm Temperature = 298.15 K For gas B…

Q: 0.64 moles of an ideal gas undergoes a couple of change processes that move the system from (P₁, V₁)…

Q: Two moles of nitrogen gas, which can be regarded as ideal with C, 28.6 J Kmol- (independent of…

A: The ideal gas equation is: PV=nRT······(1) Here, P is the pressure, V is the volume, T is the…

Q: 3 2.25 moles of an ideal gas with C, m =-R under a constant external pressure of 200.0x10³ 2 3. Pa…

Q: Two moles of an ideal gas (Cv,m = 19.7 JK¯¹ mol¯¹) originally in state 1 are taken through three…

A: The change in enthalpy (∆H) refers to the heat of a reaction under the condition of constant…

Q: 1. (Hw) A cylinder with a piston contains 0.25 mol of nitrogen at 1.80 x 10'Pa and 300 K. The…

A: The gas is first compressed isothermally one-half of its original volume. It then expands…

Q: | 2.25 moles of an ideal gas with C, m 3 =-R under a constant external pressure of 200.0x10 2 3. Pa…

A: Given data

Q: Determine the static pressure to stagnation pressure ratio associated with the following motion in…

A: At standard atmospheric condition it is given that, (a) Given speed = v = 5mph Speed of sound, c =…

Q: 4. (a) Determine the reduced pressure (P,), volume (V,), and temperature (T, ) for a 50 L sample of…

Q: Assuming that air may be treated as a mixture of ideal gases which has a mass composition 23.2%…

A: As per our guidelines we can only solve first question, please post other questions as next…

Q: Two closed tanks are connected to each other by a valve. The first tank contains oxygen (O₂, m= 2.4…

A: Note: Since you have posted a question with multiple sub-parts, we will solve the first three…

Q: 6. A gas mixture contains 2.01 mol F2 and 1.85 mol CH4 with a total pressure of 150. kPa. What is…

A: From given

Q: Prove that the difference between (CP) and (CV) for real gases is given by the following…

Q: = 4. Assume N2 behaves as perfect gas. A sample consisting of 2.00 mole of N₂ initially at pi 111…

Q: + e H2O a) Write the equations for the balance by elements and the balance of electrons. b)…

A: Part a. and b. amount of carbon in 1 mole of substrate = 2(12) = 24 g amount of carbon converted to…

Q: Gas Constant R of CO2 at 825K.

A: Gas constant is a universal constant and its value is fixed or same for all gases. It doesn't change…

Q: An automobile wheel contains air with a pressure of 3x10^5 Pa at 25 ° C. The sipop cover was removed…

A: The relation between pressure and temperature for the adiabatic process is shown below: where; P =…

Q: Gas Constant R of CO2 at 825K.

A: Gas constant is a universal constant and its value is fixed for all gases. It does not change with…

Q: 4.44. Show that a (5), = = 1 where a is the expansion coefficient and K is the isothermal…

A: This problem is based on Thermodynamics.Here, we have to define expansion coefficient and isothermal…

Q: EX4A.1- Calculate the Gibbs free energy of fusion (melting) for water [in J/mol] at T= 0°C at 58.4…

A: Fusion of water can be represented as: H2O(s)↔H2O(l) (1)

Q: What is the work of expansion when 48.6 g of D20(1) is electrolyzed to form D2(g) and O2(g) at 293 K…

Q: Metabolic engineering Consider the engineering design of microbial cell culture and growth in the…

A: Given:Reaction is: C2H5OH + aO2 + bNH3 -----> cCH3.5N0.15O0.4 + dH2O + eCO2 By mass…

Q: (¹1) Resive the coufficients of than expension, d, and compression, B, for d= =+(37) pirfut gas. B 3…

A: Alpha and beta can be calculated for perfect gas by differential of ideal gas equation.

Q: Calculate the molar volume of saturated liquid and molar volume of saturated vapor by the…

A: The aim of this question is to explain the Redlich/Kwong equation is a thermodynamic model used to…

Q: 2.25 moles of an ideal gas with Cy 3 R under a constant external pressure of 200.0x103 Pa is cooled…

Q: Stress may trigger some headaches. This could be related to increased (hypertension) or decreased…

A: Intracranial hypertension (IH) is a clinical condition that is associated with an elevation of the…

Q: Suppose that a gas obeys at low pressure the equation B * + (A + = 1 ) P PV = RT + A + where A and…

Q: 7A A mass m of a perfect gas [C=0.815 KJ/Kg K , cp=1.42 KJ/Kg K] is compressed from 0.85 m' and 105…

Q: 5.31 A McLeod gauge measures low gas pressures by com- pressing a known volume of the gas at…

A: McLeod gauge is a scientific instrument which is used to measure the very low pressure . It work…

Q: A sealed, insulated container is divided into 2 sections by a very thin membrane. Section A contains…

Q: (b) For the following equation of state, determine the Boyle temperature in terms of constants: PVm…

A: Soln Boyle's temperature is temperature at which the any real gas follows the Boyle's law i.e it…

Q: (a) For an ideal gas equation of state, prove that P P P dP = dn +=dT dv n (b) Suppose 1.000 mol of…

Q: E2A.5(b) A sample consisting of 2.00 mol of perfect gas molecules, for which Cy.m = ³R, initially at…

Q: 9a. 5.0 kg of steam are placed in a tank at 1000 kPa (abs) and 250°C. The tank is then cooled until…

A: In the given question we have to calculate the mass of the steam condensed when the tank is…

Q: 23: For the gas reaction CO (g) + O₂ (g) → CO₂ (g) Calculate the maximum volume of the CO₂ gas at 28…

A: The balanced chemical equation is: CO(g) + 1/2 O2(g) → CO2(g) In order to find the maximum volume…

Concept explainers

Kinetic-Theory of Gases

Kinetic theory of gases is the model or method which was developed in the 19th century by Maxwell and Boltzmann. This is possible as the interatomic force which is of short-range forces that are important for solids and liquids can be neglected for gases. This theory or gas law gives a molecular interpretation of the pressure and temperature of a gas and is consistent with gas laws and Avogadro’s hypothesis. This theory is very helpful to correctly explain the specific heat capacities of many gases, kinetic energy and it also explains the transport qualities such as viscosity, thermal conductivity, and diffusion with molecular parameters. As stated in the kinetic-molecular theory, the temperature of a substance or gas particle is related to the average kinetic energy of the particles of that substance. When a substance is heated, some of the absorbed energy is stored within the particles, while some of the energy increases the motion of the particles, called average kinetic energy.

Question

3.46. Calculate Z and V for sulfur hexafluoride at 75°℃_and_15_bar by the following
equations:
(a) The truncated virial equation [Eq. (3.38)] with the following experimental values
of virial coefficients:
B = −194 cm³.mol-1 C= 15,300 cm 6.mol-²
(b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized
Pitzer correlation [Eqs. (3.58)-(3.62)]

PV
RT
Z=-
=
B C
1+ +
V
V²
PV
Z= =1+
RT
B=
BP c
RTC
BO=0.083
(3.58)
0.422
T1.6
r
BP
RT
B=B⁰+wB¹ (3.59)
(3.61) B¹ = 0.139 -
0.172
T4.2
r
(3.38)
(3.36)
(3.62)

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Guideline message

VIEW

Step 2: Determine Z and V for Sulfur hexachloride

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 5 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

pls answer in 4 decimal places
(1) Perive the coefficints of thamal expansion, d, and compression, B, for в, d= perfut gas. -- + ( 37 ) B = - ) Y = molar извести
A certain gas obey's the following equation of state: RT P = V – b V²T a Write the constants a andb in terms of the critical P V. and T?
Initial Pressure = 125 kPa, Initial Volume = 125 mL, Final Pressure = 100. kPa, Final Volume = 100. mL and Final Temperature = 75.0oC. Solve for Initial Temperature. Answer: Unit: Blank 1: Blank 2:
A rigid vessel of volume 0.2m³ contains 10 kg of (liquid + vapor) water at 200°C. What are the pressure and internal energy of the water?
2.20 mol of N3 at 12.0 °C and 6.45 bar undergoes a transformation to the state described by 335 "Cand 1.95 bar. Part A Calculate AS Cr 3/ K) - 30.81 - 11.87 x 10 +2.3968 x 10--1.0176 x 10- Express your answer with the appropriate units. J AS - 48.86 K
b) Connecting a physical protocol to quantitative expressions: In medical treatments, you often never work with pure oxygen. [In fact, breathing high concentrations of oxygen is toxic and can lead to hyperoxia]. Suppose you would like to prepare a mixture of nitrogen and oxygen gases. You have a 1.0-L flask of N₂(g) stored at 2.1 bar and T = 50.°C and a 2.0-L flask of O₂ (g) stored at 1.0 bar and T = 20.°C. Assuming ideal gas behavior, what is the final pressure (in bars) if you combine the two flasks into a 5.0-L flask at room temperature?
Calculate the value of cp at 298 K and 1 atm pressure predicted for Cl, and NO, by the classical equipartition theorem. (Enter your answers to at least two decimal places.) Cp(Cl)) = J mol 1 K1 Cp(NO,) = J mol K1 The actual heat capacities of C and NO, are 33.91 and 36.97 J molK, respectively. Calculate the fraction (expressed as a percentage) of the measured value that arises from vibrational motions. vibrational contribution to cp(Cl,) = vibrational contribution to cp(NO,) =
At low pressures, the compressibility factor of a van der Waals gas is given by the equation: Z = 1+ (b-a/RT) P/RT Calculate ΔG (in units J/mol) associated with the isothermal compression of nitrogen gas at 298 K from 10 bar to 25 bar. The van der Waals constants of nitrogen gas are a = 1.408 L^2-bar-mol and b = 0.03913 L-mol^-1