3. Pure (-)-mandelic acid has a specific rotation of -160° (same conditions and temperature as sample above). What is the % optical purity of the sample above?

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Dr. VMV weighed out 1.02 g of menthol and dissolved it into 10.0 mL of absolute
ethanol in a 10.0 mL volumetric flask. The optical rotation for this solution was
obtained in a cell with a 50 mm optical path length, found to be -2.508°, using the Na
D-line at 25.1 °C. What is the specific rotation?
2. 0.5 g of optically-enriched (-)-mandelic acid was dissolved in 10 mL of absolute
ethanol. Using a 1 dm polarimeter tube, the observed optical rotation was found to
be -6.8°. What is the specific rotation?
3. Pure (-)-mandelic acid has a specific rotation of -160° (same conditions and
temperature as sample above). What is the % optical purity of the sample above?
Transcribed Image Text:Dr. VMV weighed out 1.02 g of menthol and dissolved it into 10.0 mL of absolute ethanol in a 10.0 mL volumetric flask. The optical rotation for this solution was obtained in a cell with a 50 mm optical path length, found to be -2.508°, using the Na D-line at 25.1 °C. What is the specific rotation? 2. 0.5 g of optically-enriched (-)-mandelic acid was dissolved in 10 mL of absolute ethanol. Using a 1 dm polarimeter tube, the observed optical rotation was found to be -6.8°. What is the specific rotation? 3. Pure (-)-mandelic acid has a specific rotation of -160° (same conditions and temperature as sample above). What is the % optical purity of the sample above?
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