3. For the reaction A(g + B(g) + C(g) → D(g) The following data were obtained at constant temperature A series of four experiments were run at different concentrations, and the initial rates of D(g) formation were determined. From these data, obtain the reaction orders with respect to A, B and C. Write the rate law and determine the rate constant. What is the overall order of the reaction? Experiment 1 Initial [A] Initial [B]_ Initial [C] Initial Rate (M/s) 0.0500 0.0500 0.0100 6.25 х 10-3 2 0.1000 0.0500 0.0100 1.25 x 10-2 3 0.1000 0.1000 0.0100 5.00 x 10-2 4 0.0500 0.0500 0.0200 6.25 x 10-3

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.50QE
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3.
For the reaction
A(g + B(g) + Cg) → Dg)
The following data were obtained at constant temperature
A series of four experiments were run at different concentrations, and the initial rates of D(g)
formation were determined. From these data, obtain the reaction orders with respect to A, B and
C. Write the rate law and determine the rate constant. What is the overall order of the reaction?
Experiment
Initial [A]
Initial [B]
Initial [C]
Initial Rate (M/s)
1
0.0500
0.0500
0.0100
6.25 x 10-3
0.1000
0.0500
0.0100
1.25 х 10-2
3
0.1000
0.1000
0.0100
5.00 x 10-2
4
0.0500
0.0500
0.0200
6.25 х 10-3
If there is no change in the concentrations, why is the equilibrium state considered dynamic
Transcribed Image Text:3. For the reaction A(g + B(g) + Cg) → Dg) The following data were obtained at constant temperature A series of four experiments were run at different concentrations, and the initial rates of D(g) formation were determined. From these data, obtain the reaction orders with respect to A, B and C. Write the rate law and determine the rate constant. What is the overall order of the reaction? Experiment Initial [A] Initial [B] Initial [C] Initial Rate (M/s) 1 0.0500 0.0500 0.0100 6.25 x 10-3 0.1000 0.0500 0.0100 1.25 х 10-2 3 0.1000 0.1000 0.0100 5.00 x 10-2 4 0.0500 0.0500 0.0200 6.25 х 10-3 If there is no change in the concentrations, why is the equilibrium state considered dynamic
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