3. Alkenes provide many ways for incorporating oxygen atoms at specific locations in our molecule. Follow prompts i-iii to complete the 2-3 step synthesis problems below. i. Compare the structure of the starting material and the final product. Find the carbons from LİCH2CH3 in the final product and circle them. ii. Based on the location of the new bond formed in the final product, did LICH2CH3 attack a carbonyl or epoxide electrophile? Draw the full structure of this electrophile in the Electrophile box. Based on the location of the oxygen in the electrophile, identify which of the following reactions should be applied to the alkene starting material, and write the appropriate reagents in the box for Rxn 1: hydration, oxymercuration-reduction, hydroboration- oxidation, epoxidation, ozonolysis. Draw the structure of Intermediate Product 1. If Intermediate Product 1 and Electrophile are different, provide the missing reagents for Rxn 2. If they match, write NA in the box for Rxn 2. iii. iv. Starting Material Intermediate Rxn 1 Rxn 2 Electrophile Final Product Product 1 OH LİCH¿CH3 HO LİCH¿CH3 Но LİCH¿CH3 OH LİCH¿CH3 LİCH¿CH3 1 1

3. Alkenes provide many ways for incorporating oxygen atoms at specific locations in our molecule. Follow prompts i-iii to complete the 2-3 step synthesis problems below. i. Compare the structure of the starting material and the final product. Find the carbons from LİCH2CH3 in the final product and circle them. ii. Based on the location of the new bond formed in the final product, did LICH2CH3 attack a carbonyl or epoxide electrophile? Draw the full structure of this electrophile in the Electrophile box. Based on the location of the oxygen in the electrophile, identify which of the following reactions should be applied to the alkene starting material, and write the appropriate reagents in the box for Rxn 1: hydration, oxymercuration-reduction, hydroboration- oxidation, epoxidation, ozonolysis. Draw the structure of Intermediate Product 1. If Intermediate Product 1 and Electrophile are different, provide the missing reagents for Rxn 2. If they match, write NA in the box for Rxn 2. iii. iv. Starting Material Intermediate Rxn 1 Rxn 2 Electrophile Final Product Product 1 OH LİCH¿CH3 HO LİCH¿CH3 Но LİCH¿CH3 OH LİCH¿CH3 LİCH¿CH3 1 1

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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