3. (a) What is meant by coordinative unsaturation? How is it related to catalytic properties of inorganic complexes? Furnish two methods for generation of coordinative unsaturated compounds. (b) Predict the product and chemistry involved in the following reactions: (i) [Rh(CO)₂Cl₂] + CH3I (ii) Pt(PPh3)3 + CF3I (iii) Ru(PPh3)2(CO)3 + H₂-

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3. (a) What is meant by coordinative unsaturation? How is it
related to catalytic properties of inorganic complexes?
Furnish two methods for generation of coordinative
unsaturated compounds.
(b) Predict the product and chemistry involved in the following
reactions:
(i) [Rh(CO)₂Cl₂] + CH3I
(ii) Pt(PPh3)3 + CF3I
(iii) Ru(PPh3)2(CO)3 + H₂-
(iv) CH3Mn(CO)s + C6H5NH2-
(c) "Benzyl cinnamate gives the dihydro-derivative on
hydrogenation in presence of Wilkinson's catalyst, whereas
hydrogenation on a Pd/H₂ (high pressure and temperature)
produces 3-phenylpropanoic acid and toluene" Explain.
Transcribed Image Text:3. (a) What is meant by coordinative unsaturation? How is it related to catalytic properties of inorganic complexes? Furnish two methods for generation of coordinative unsaturated compounds. (b) Predict the product and chemistry involved in the following reactions: (i) [Rh(CO)₂Cl₂] + CH3I (ii) Pt(PPh3)3 + CF3I (iii) Ru(PPh3)2(CO)3 + H₂- (iv) CH3Mn(CO)s + C6H5NH2- (c) "Benzyl cinnamate gives the dihydro-derivative on hydrogenation in presence of Wilkinson's catalyst, whereas hydrogenation on a Pd/H₂ (high pressure and temperature) produces 3-phenylpropanoic acid and toluene" Explain.
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