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3) The chemical structure for an asparagine residue in a peptide is given below. NH₂ ZI 'N' H NH 8.75 ppm, NH₂ 7.59, 6.91 ppm, СßH 2.83, 2.75 ppm, CaH 4.75 ppm (i) (ii) (iii) (iv) Draw out a 1-D ¹H NMR spectrum for this residue include the multiplicity of each signal. For simplicity in your drawing take that the coupling constant for the NH-CH >> CH-CH. Show the approx. relative height of the signals and clearly assign each peak in the spectrum. Draw out a 1H-1H COSY spectrum for this residue. Clearly assign each diagonal peak and show all the cross peaks in the spectrum. How many spin systems are in the residue? Draw in the extra peaks that would occur in the ¹H-¹H TOCSY spectrum for this residue

3) The chemical structure for an asparagine residue in a peptide is given below. NH₂ ZI 'N' H NH 8.75 ppm, NH₂ 7.59, 6.91 ppm, СßH 2.83, 2.75 ppm, CaH 4.75 ppm (i) (ii) (iii) (iv) Draw out a 1-D ¹H NMR spectrum for this residue include the multiplicity of each signal. For simplicity in your drawing take that the coupling constant for the NH-CH >> CH-CH. Show the approx. relative height of the signals and clearly assign each peak in the spectrum. Draw out a 1H-1H COSY spectrum for this residue. Clearly assign each diagonal peak and show all the cross peaks in the spectrum. How many spin systems are in the residue? Draw in the extra peaks that would occur in the ¹H-¹H TOCSY spectrum for this residue

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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3) The chemical structure for an asparagine residue in a peptide is given below. NH₂ ZI 'N' H NH 8.75 ppm, NH₂ 7.59, 6.91 ppm, СßH 2.83, 2.75 ppm, CaH 4.75 ppm (i) (ii) (iii) (iv) Draw out a 1-D ¹H NMR spectrum for this residue include the multiplicity of each signal. For simplicity in your drawing take that the coupling constant for the NH-CH >> CH-CH. Show the approx. relative height of the signals and clearly assign each peak in the spectrum. Draw out a 1H-1H COSY spectrum for this residue. Clearly assign each diagonal peak and show all the cross peaks in the spectrum. How many spin systems are in the residue? Draw in the extra peaks that would occur in the ¹H-¹H TOCSY spectrum for this residue
Transcribed Image Text:3) The chemical structure for an asparagine residue in a peptide is given below. NH₂ ZI 'N' H NH 8.75 ppm, NH₂ 7.59, 6.91 ppm, СßH 2.83, 2.75 ppm, CaH 4.75 ppm (i) (ii) (iii) (iv) Draw out a 1-D ¹H NMR spectrum for this residue include the multiplicity of each signal. For simplicity in your drawing take that the coupling constant for the NH-CH >> CH-CH. Show the approx. relative height of the signals and clearly assign each peak in the spectrum. Draw out a 1H-1H COSY spectrum for this residue. Clearly assign each diagonal peak and show all the cross peaks in the spectrum. How many spin systems are in the residue? Draw in the extra peaks that would occur in the ¹H-¹H TOCSY spectrum for this residue
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