3) Provide the Fischer projection of the compound shown below? Br Br 4) Is the following alkene E, Z, or neither? OMe A) E B) Z C) Neither D) It is one or the other, but which is impossible to determine from the information given. 5) What is the relationship between the two structures shown? Br Br H and CI H Η H A) same compound B) enantiomers C) diastereomers D) none of these ||
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- 5) Use compounds X, Y and Z (shown below) to answer the following questions. H. H3C" "CH3 ОН CH3 compound X compound Y compound Z a) Is compound X classified as cis, trans or neither? b) Is compound Y classified as E, Z or neither? c) Is compound Z classified as R, S or neither? d) Are compounds X and Y constitutional isomers of each other? (YES or NO) e) Are compounds Y and Z constitutional isomers of each other? (YES or NO) f) Classify compound Y as a primary, secondary or tertiary alcohol. g) Which compound(s) is(are) chiral? h) Give the IUPAC name for compound Z, omitting the absolute configuration (R or S) designation. i) In the indicated spaces below, draw stereoisomers of compounds X, Y and Z. stereoisomer of compound X stereoisomer of compound Y stereoisomer of compound ZWhat is the specific relationship between each of the following pairs of molecules? Label as either: same, constitutional isomers, enantiomers, diastereomers, conformers, or different соmpounds. a) b) Br Br LCH3 H3C H. CH, H,C "CH3 CI H. H c) CI ОН d) Br CH3 "CH3 OH CI Br e) CH3 CH3 f) Br OCH3 H. OCH3 Br g) h) H CH3 НО CI CI HO Но CH3 CH3 CH3 H i) CO,H CO,H j) CO,H CO,H H- -ОН Но -H H- OH OH НО H- OH H- OH но -H OH Но H ОН H CO2H CO,H CH,OH CH,OHa) Draw the two chair conformations for the compound below, indicating which is more stable. OH CHO b) This molecule is a compound with an intense flowery odor used in perfumes, but it isomerizes rapidly in base to its odorless diastereoisomer. Draw the chair conformation of this diastereoisomer and explain why the isomerization occurs readily.
- Draw each compound in its most symmetric conformation, star (*) any asymmetric carbon atoms, and draw any mirror planes.Label any meso compounds. You may use Fischer projections if you prefer.(a)(R, R)-2,3-dibromobutaneStrain of one Strain of one 1,3-diaxial interaction 1,3-diaxial interaction Strain of one 1,3-diaxial interaction H X Ph (C6H5) CO,H CN F 0.12 Me 0.9 1.5 Cl 0.7 0.1 0.25 Et 0.95 Br 0.25 i-Pr 1.1 OH 0.5 t-Bu 2.71E.) Which of the following two conformers is lower in energy? Both conformers are of equal enery O A Conformer A is lower in energy. B Conformer B is lower in energy. It cannot be determined
- H3C --CH3 Which structure(s) below represent(s) the diastereoisomer(s) of the compound on the picture? Br CH3 C CH3 A B CH3 H3C 'Br Br CH3 H3C Br CH3 E CH3 --CH3 H3C.. Br Br Br H3C -.just problem 5.26 please8) For each of the pairs of molecules drawn below, place letters in the corner boxes corresponding to all accurate descriptions of the relationship between the two molecules. a) b) c) HO F A enantiomers F all letters that apply H H OH Вад CI all letters that apply all letters that apply B diastereomers C different conformations of the same molecule D identical conformations of the same molecule E constitutional isomers F stereoisomers G different molecules H both are chiral I neither is chiral