2CH3CH2OH(1) + 602(g)—4CО2(в) + 6H20(g) Based on the standard free energies of formation given in the table below, what is the standard ree energy change for this reaction? AG Substance kJ/mol) |СHз CH2ОH(1)| — 174.9

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The standard free energy of formation, AG: , of a substance is
the free energy change for the formation of one mole of the
substance from the component elements in their standard
states. These values are applicable at 25°C and are found in
thermodynamic tables.
The value of AG; for a substance gives a measure of the
thermodynamic stability with respect to the component
elements. Negative values for a formation reaction indicate
thermodynamic stability of the product. In other words, the
compound formed does not spontaneously decompose back
into the component elements. Positive values for a formation
reaction indicate thermodynamic instability of the product.
Thus, the compound will spontaneously decompose, though
the rate may be slow.
The sign of AG: can be used to predict the feasibility of
synthesizing a substance from its component elements. The
standard free energy change for a reaction, AG°, is a state
function and can be calculated from the standard free energies
of formation as follows:
ΔG Ση, AG; (products) -Ση ΔG; (reactants)
where np and n, represent the stoichiometric coefficients in
the balanced chemical equation for the reactants and products
respectively.
Transcribed Image Text:The standard free energy of formation, AG: , of a substance is the free energy change for the formation of one mole of the substance from the component elements in their standard states. These values are applicable at 25°C and are found in thermodynamic tables. The value of AG; for a substance gives a measure of the thermodynamic stability with respect to the component elements. Negative values for a formation reaction indicate thermodynamic stability of the product. In other words, the compound formed does not spontaneously decompose back into the component elements. Positive values for a formation reaction indicate thermodynamic instability of the product. Thus, the compound will spontaneously decompose, though the rate may be slow. The sign of AG: can be used to predict the feasibility of synthesizing a substance from its component elements. The standard free energy change for a reaction, AG°, is a state function and can be calculated from the standard free energies of formation as follows: ΔG Ση, AG; (products) -Ση ΔG; (reactants) where np and n, represent the stoichiometric coefficients in the balanced chemical equation for the reactants and products respectively.
When ethanol (CH3CH2OH) is combusted, such as when in a gasoline blend, the following
reaction occurs:
2CH3CH2OH(1) + 602(g)—4CО2 (8) + 6H20(g)
Based on the standard free energies of formation given in the table below, what is the standard
free energy change for this reaction?
AG
Substance
kJ/mol)
CH3 CH2 OH(1) –174.9
O2 (g)
CO2 (g)
-394.4
H2O(g)
-228.6
Express your answer to one decimal place and include the appropriate units.
Transcribed Image Text:When ethanol (CH3CH2OH) is combusted, such as when in a gasoline blend, the following reaction occurs: 2CH3CH2OH(1) + 602(g)—4CО2 (8) + 6H20(g) Based on the standard free energies of formation given in the table below, what is the standard free energy change for this reaction? AG Substance kJ/mol) CH3 CH2 OH(1) –174.9 O2 (g) CO2 (g) -394.4 H2O(g) -228.6 Express your answer to one decimal place and include the appropriate units.
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