25°C in a cylinder fitted with a movable piston expañds against a constant external pressure of 1.00 atm. At equilibrium, the pressure and volume of the gas are 1.00 atm and 23.5 L, respectively. (a) Calculate the final temperature of the sample. (b) Calculate the values of q, w, and AU for the process. 3.14 An ideal gas is compressed isothermally from 2.0 atm and 2.0 L to 4.0 atm and 1.0 L. Calculate the values of Δ U and ΔΗ if the process is carried out (a) reversibly and (b) irreversibly. 5 3.15 Explain the energy changes at the molecular level when liquid acetone is converted to vapor at its boiling point. 3.16 A piece of potassium metal is added to water in a beaker. The reaction that takes place is 2K (s) + 2H20) 2KOH (aq) + H2(g) Predict the signs of w, q,AU, and ΔΗ. 3.17 At 373.15 K and 1 atm, the molar volume of liquid water and steam are 1.88 x 10-5 m3 and 3.06 10-2 m, respectively. Given that the heat of vaporization of water is 40.79 kJ mol-1, calculate and Δ U for l mole in the following the values of process: H20(4,373.15 K, 1 atm) H20(g, 373.15 K, 1 atm)

25°C in a cylinder fitted with a movable piston expañds against a constant external pressure of 1.00 atm. At equilibrium, the pressure and volume of the gas are 1.00 atm and 23.5 L, respectively. (a) Calculate the final temperature of the sample. (b) Calculate the values of q, w, and AU for the process. 3.14 An ideal gas is compressed isothermally from 2.0 atm and 2.0 L to 4.0 atm and 1.0 L. Calculate the values of Δ U and ΔΗ if the process is carried out (a) reversibly and (b) irreversibly. 5 3.15 Explain the energy changes at the molecular level when liquid acetone is converted to vapor at its boiling point. 3.16 A piece of potassium metal is added to water in a beaker. The reaction that takes place is 2K (s) + 2H20) 2KOH (aq) + H2(g) Predict the signs of w, q,AU, and ΔΗ. 3.17 At 373.15 K and 1 atm, the molar volume of liquid water and steam are 1.88 x 10-5 m3 and 3.06 10-2 m, respectively. Given that the heat of vaporization of water is 40.79 kJ mol-1, calculate and Δ U for l mole in the following the values of process: H20(4,373.15 K, 1 atm) H20(g, 373.15 K, 1 atm)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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