(25a) The equilibrium constant, K, for the following reaction is 2.10×10-2 at 514 K. PCl5 (g) PCl3 (g) + Cl2 (g) An equilibrium mixture of the three gases in a 18.3 L container at 514 K contains 0.271 M PCl5,   7.54×10-2 M PCl3 and 7.54×10-2 M Cl2. What will be the concentrations of the three gases once equilibrium has been reestablished, if the equilibrium mixture is compressed at constant temperature to a volume of 9.11 L? [PCl5] = M [PCl3] = M [Cl2] = M

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(25a) The equilibrium constant, K, for the following reaction is 2.10×10-2 at 514 K.

PCl5

      (g)

PCl3

      (g) +

Cl2

    (g)


An equilibrium mixture of the three gases in a 18.3 L container at 514 K contains 0.271 M PCl5,   7.54×10-2 M PCl3 and 7.54×10-2 M Cl2. What will be the concentrations of the three gases once equilibrium has been reestablished, if the equilibrium mixture is compressed at constant temperature to a volume of 9.11 L?

[PCl5] = M
[PCl3] = M
[Cl2] = M

(b) The equilibrium constant, K, for the following reaction is 1.01×10-2 at 694 K.

NH4I(s) NH3(g) + HI(g)

An equilibrium mixture in a 17.0 L container at 694 K contains 0.254 mol NH4I(s), 0.140 M NH3 and 7.21×10-2 M HI. What will be the concentrations of the two gases once equilibrium has been reestablished, if the equilibrium mixture is compressed at constant temperature to a volume of 8.91 L?

[NH3] = M
[HI] = M

 

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