25. The following data was obtained from a kinetics experiment, changing the concentrations of the reactants. [I]o (M) 2.0 × 10-3 [OC] (M) [OH] (M) Initial Rate (M s¹) 1.5 × 10-3 1.00 1.8 × 104 4.0 ×10-3 1.5 × 10-3 1.00 3.6 × 104 2.0 × 10-3 3.0 × 10-3 2.00 1.8 × 104 4.0 × 10-3 3.0 × 10-3 1.00 7.2 × 104 By deriving the rate laws, decide whether the following mechanism is plausible. OCI¯ + H2O = HOCI + OH¯ I¯ + HOCI → HOI + Cl¯ HOI + OH → H₂O + OI¯
25. The following data was obtained from a kinetics experiment, changing the concentrations of the reactants. [I]o (M) 2.0 × 10-3 [OC] (M) [OH] (M) Initial Rate (M s¹) 1.5 × 10-3 1.00 1.8 × 104 4.0 ×10-3 1.5 × 10-3 1.00 3.6 × 104 2.0 × 10-3 3.0 × 10-3 2.00 1.8 × 104 4.0 × 10-3 3.0 × 10-3 1.00 7.2 × 104 By deriving the rate laws, decide whether the following mechanism is plausible. OCI¯ + H2O = HOCI + OH¯ I¯ + HOCI → HOI + Cl¯ HOI + OH → H₂O + OI¯
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.18P
Related questions
Question
![25. The following data was obtained from a kinetics experiment, changing the concentrations of
the reactants.
[I]o (M)
2.0 × 10-3
[OC] (M)
[OH] (M)
Initial Rate (M s¹)
1.5 × 10-3
1.00
1.8 × 104
4.0 ×10-3
1.5 × 10-3
1.00
3.6 × 104
2.0 × 10-3
3.0 × 10-3
2.00
1.8 × 104
4.0 × 10-3
3.0 × 10-3
1.00
7.2 × 104
By deriving the rate laws, decide whether the following mechanism is plausible.
OCI¯ + H2O = HOCI + OH¯
I¯ + HOCI → HOI + Cl¯
HOI + OH → H₂O + OI¯](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2dfd94d7-ef18-4a91-9ec9-63733918bf41%2F98ea6324-0a1d-4e0e-8241-8541fc0074ee%2Fk0iseo_processed.jpeg&w=3840&q=75)
Transcribed Image Text:25. The following data was obtained from a kinetics experiment, changing the concentrations of
the reactants.
[I]o (M)
2.0 × 10-3
[OC] (M)
[OH] (M)
Initial Rate (M s¹)
1.5 × 10-3
1.00
1.8 × 104
4.0 ×10-3
1.5 × 10-3
1.00
3.6 × 104
2.0 × 10-3
3.0 × 10-3
2.00
1.8 × 104
4.0 × 10-3
3.0 × 10-3
1.00
7.2 × 104
By deriving the rate laws, decide whether the following mechanism is plausible.
OCI¯ + H2O = HOCI + OH¯
I¯ + HOCI → HOI + Cl¯
HOI + OH → H₂O + OI¯
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