235L-1. Write a mechanism to explain the formation of the 1,2-dioxetanedione intermediate upon treating divanillyl oxalate with hydrogen peroxide and sodium hydroxide (Scheme 4). Hint: Both of the singly-bonded oxygen atoms in the 1,2-dioxetanedione are derived from hydrogen peroxide.

235L-1. Write a mechanism to explain the formation of the 1,2-dioxetanedione intermediate upon treating divanillyl oxalate with hydrogen peroxide and sodium hydroxide (Scheme 4). Hint: Both of the singly-bonded oxygen atoms in the 1,2-dioxetanedione are derived from hydrogen peroxide.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

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Problem 34MP: Amino acids can be prepared by reaction of alkyl halides with diethyl acetamidomalonate, followed by...

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Question

235L-1.
Write a mechanism to explain the formation of the 1,2-dioxetanedione
intermediate upon treating divanillyl oxalate with hydrogen peroxide and sodium hydroxide
(Scheme 4). Hint: Both of the singly-bonded oxygen atoms in the 1,2-dioxetanedione are derived
from hydrogen peroxide.

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