Homework Help is Here – Start Your Trial Now!
Engineering
Chemical Engineering
23.2b Consider the following mechanism for the thermal decomposition of R₂: (1) R₂ → R+R (2) R+ R₂ → PB+R' (3) R'→PA+R (4) R+R PA + PB where R₂, PA, PB are stable hydrocarbons and R and R' are radicals. Find the dependence of the rate of decomposition of R₂ on the concentration of R₂. 1/2 23.2 d[R₂] dt =-k₁ [R₂] -k₂| k₁ k₁ [R₂] 3/2

23.2b Consider the following mechanism for the thermal decomposition of R₂: (1) R₂ → R+R (2) R+ R₂ → PB+R' (3) R'→PA+R (4) R+R PA + PB where R₂, PA, PB are stable hydrocarbons and R and R' are radicals. Find the dependence of the rate of decomposition of R₂ on the concentration of R₂. 1/2 23.2 d[R₂] dt =-k₁ [R₂] -k₂| k₁ k₁ [R₂] 3/2

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
See similar textbooks
icon
Related questions
Question
23.2a A slightly different mechanism for the decomposition of N₂O5 from that in Exercise 23.1b has also been proposed. It differs only in the last step, which is replaced by (3) NO+NO3 → NO₂ + NO₂ k₂ Show that this mechanism leads to the same overall rate law. 23.2b Consider the following mechanism for the thermal decomposition of R₂: (1) R₂ → R+R (2) R+ R₂ → PB+R' (3) R' → PA+R (4) R+R →PA + PB where R₂, PA, PÅ are stable hydrocarbons and R and R' are radicals. Find the dependence of the rate of decomposition of R₂ on the concentration of R₂. 1/2 -k₁ [R₂]-k₂ 23.2 d[R₂] dt k₁ k₁ [R₂]³/2.
Transcribed Image Text:23.2a A slightly different mechanism for the decomposition of N₂O5 from that in Exercise 23.1b has also been proposed. It differs only in the last step, which is replaced by (3) NO+NO3 → NO₂ + NO₂ k₂ Show that this mechanism leads to the same overall rate law. 23.2b Consider the following mechanism for the thermal decomposition of R₂: (1) R₂ → R+R (2) R+ R₂ → PB+R' (3) R' → PA+R (4) R+R →PA + PB where R₂, PA, PÅ are stable hydrocarbons and R and R' are radicals. Find the dependence of the rate of decomposition of R₂ on the concentration of R₂. 1/2 -k₁ [R₂]-k₂ 23.2 d[R₂] dt k₁ k₁ [R₂]³/2.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The
SEE MORE TEXTBOOKS