23) H Provide the structure of the major organic product in the reaction shown below. 1. 2 CH3CH,CH,MgBr OCH₂CH3 2. H3O+

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23)
Provide the structure of the major organic product in the reaction shown below.
1. 2 CH3CH₂CH₂MgBr
H
OCH₂CH3
2. H3O+
24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?
(a) Sn/conc. HC1 (b) Na/NH3 (c) H₂/Raney Ni (d) NaBH4/EtOH (e) Zn-Hg/HCl(aq)
25) Circle alcohol(s), show the "strongest acid" due to "resonance-stabilized" conjugate
base.
H
1-propen-1-ol
cyclohexanol
phenol
1-pentanol
can be preferred to produce aldehyde by the oxidation of 2-methyl-1-
26) The reagent(s)
pentanol?
(a) NaOCI/TEMPO
(d) KMnO4.
(c) both PCC and Swern
(b) CrO3/H₂SO4
27) Which one of the following reactions is Fischer-Esterification?
(a) 1-propanol/H3PO4
(d) 1-propanol/H₂SO4
(b) 1-butanol/CH3CO₂H
(e) 1-butanal/EtCO₂H
(c) butan-2,3-diol/HNO3
reactive towards Lucas reagent (HCl/ZnCl₂)?
Transcribed Image Text:23) Provide the structure of the major organic product in the reaction shown below. 1. 2 CH3CH₂CH₂MgBr H OCH₂CH3 2. H3O+ 24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes? (a) Sn/conc. HC1 (b) Na/NH3 (c) H₂/Raney Ni (d) NaBH4/EtOH (e) Zn-Hg/HCl(aq) 25) Circle alcohol(s), show the "strongest acid" due to "resonance-stabilized" conjugate base. H 1-propen-1-ol cyclohexanol phenol 1-pentanol can be preferred to produce aldehyde by the oxidation of 2-methyl-1- 26) The reagent(s) pentanol? (a) NaOCI/TEMPO (d) KMnO4. (c) both PCC and Swern (b) CrO3/H₂SO4 27) Which one of the following reactions is Fischer-Esterification? (a) 1-propanol/H3PO4 (d) 1-propanol/H₂SO4 (b) 1-butanol/CH3CO₂H (e) 1-butanal/EtCO₂H (c) butan-2,3-diol/HNO3 reactive towards Lucas reagent (HCl/ZnCl₂)?
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