22) what would be the alcohol product if MeMgBr/ether &H3O+ are added to 3-hexanone ? And 24-25 24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?(a) Sn/conc. HCI(b) Na/NH3(c) H2/Raney Ni(d) NaBH4/E1OH (e) Zn-Hg/HCl(aq)25) Circle alcohol(s), show the "strongest acid" due to “resonance-stabilized" conjugatebase.1-propen-1-olcyclohexanolphenol1-pentanolcan be preferred to produce aldehyde by the oxidation of 2-methyl-1-26) The reagent(s)pentanol?a) NaOCI/TEMPO(b) CrO3/H2SO4(c) both PCC and Swern(d) KMNO4.27) Which one of the following reactions is Fischer-Esterification?(b) 1-butanol/CH;CO,H(e) 1-butanal/EtCO,H(c) butan-2,3-diol/HNO3а) 1-propanol/H;PО,d) 1-propanol/H,S04-8) Circle the alcohol that is the most reactive towards Lucas reagent (HCl/ZnCl,)?HO,HO,HOP) Circle the "ether(s)" that need(s) excess HBr for the "ether-cleavage" process. (b) 3-ethyl-3-hexanol(a) 3-methyl-2-hexanolhexanol.(c) 3-methyl-3-hexanol(d) 3-methyl-1-23)Provide the structure of the major organic product in the reaction shown below1. 2 CH3CH2CHMgBrH3 CHz CHz CT nOCH2CH32. H30*3° alcohul24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?(a) Sn/conc. HC1(b) Na/NH3(c) H2/Raney Ni(d) NABH4/EtOH (e) Zn-Hg/HCl(aq)25) Circle alcohol(s), show the "strongest acid" due to "resonance-stabilized" conjugatebase.1-propen-1-olcyclohexanolphenol1-pentanolcan be preferred to produce aldehyde by the oxidation of 2-meth=5) The reagent(s)pentanol?NaOCI/TEMPO(b) CrO3/H2SO4(c) both PCC and Swern(d) KMNO4.Which one of the following reactions is Fischer-Esterification?

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22) what would be the alcohol product if MeMgBr/ether &H3O+ are added to 3-hexanone ?

Organic Chemistry

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Chapter22: Carbonyl Alpha-substitution Reactions

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Question

22) what would be the alcohol product if MeMgBr/ether &H3O+ are added to 3-hexanone ? And 24-25

24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?
(a) Sn/conc. HCI
(b) Na/NH3
(c) H2/Raney Ni
(d) NaBH4/E1OH (e) Zn-Hg/HCl(aq)
25) Circle alcohol(s), show the "strongest acid" due to “resonance-stabilized" conjugate
base.
1-propen-1-ol
cyclohexanol
phenol
1-pentanol
can be preferred to produce aldehyde by the oxidation of 2-methyl-1-
26) The reagent(s)
pentanol?
a) NaOCI/TEMPO
(b) CrO3/H2SO4
(c) both PCC and Swern
(d) KMNO4.
27) Which one of the following reactions is Fischer-Esterification?
(b) 1-butanol/CH;CO,H
(e) 1-butanal/EtCO,H
(c) butan-2,3-diol/HNO3
а) 1-propanol/H;PО,
d) 1-propanol/H,S04
-8) Circle the alcohol that is the most reactive towards Lucas reagent (HCl/ZnCl,)?
HO,
HO,
HO
P) Circle the "ether(s)" that need(s) excess HBr for the "ether-cleavage" process.

(b) 3-ethyl-3-hexanol
(a) 3-methyl-2-hexanol
hexanol.
(c) 3-methyl-3-hexanol
(d) 3-methyl-1-
23)
Provide the structure of the major organic product in the reaction shown below
1. 2 CH3CH2CHMgBr
H3 CHz CHz CT n
OCH2CH3
2. H30*
3° alcohul
24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?
(a) Sn/conc. HC1
(b) Na/NH3
(c) H2/Raney Ni
(d) NABH4/EtOH (e) Zn-Hg/HCl(aq)
25) Circle alcohol(s), show the "strongest acid" due to "resonance-stabilized" conjugate
base.
1-propen-1-ol
cyclohexanol
phenol
1-pentanol
can be preferred to produce aldehyde by the oxidation of 2-meth=
5) The reagent(s)
pentanol?
NaOCI/TEMPO
(b) CrO3/H2SO4
(c) both PCC and Swern
(d) KMNO4.
Which one of the following reactions is Fischer-Esterification?

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