Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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22) what would be the alcohol product if MeMgBr/ether &H3O+ are added to 3-hexanone ?
And 24-25
Transcribed Image Text:24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?
(a) Sn/conc. HCI
(b) Na/NH3
(c) H2/Raney Ni
(d) NaBH4/E1OH (e) Zn-Hg/HCl(aq)
25) Circle alcohol(s), show the "strongest acid" due to “resonance-stabilized" conjugate
base.
1-propen-1-ol
cyclohexanol
phenol
1-pentanol
can be preferred to produce aldehyde by the oxidation of 2-methyl-1-
26) The reagent(s)
pentanol?
a) NaOCI/TEMPO
(b) CrO3/H2SO4
(c) both PCC and Swern
(d) KMNO4.
27) Which one of the following reactions is Fischer-Esterification?
(b) 1-butanol/CH;CO,H
(e) 1-butanal/EtCO,H
(c) butan-2,3-diol/HNO3
а) 1-propanol/H;PО,
d) 1-propanol/H,S04
-8) Circle the alcohol that is the most reactive towards Lucas reagent (HCl/ZnCl,)?
HO,
HO,
HO
P) Circle the "ether(s)" that need(s) excess HBr for the "ether-cleavage" process.
Transcribed Image Text:(b) 3-ethyl-3-hexanol
(a) 3-methyl-2-hexanol
hexanol.
(c) 3-methyl-3-hexanol
(d) 3-methyl-1-
23)
Provide the structure of the major organic product in the reaction shown below
1. 2 CH3CH2CHMgBr
H3 CHz CHz CT n
OCH2CH3
2. H30*
3° alcohul
24) Which of the reducing agents produces 1,4-cyclohexadiene analogs from benzenes?
(a) Sn/conc. HC1
(b) Na/NH3
(c) H2/Raney Ni
(d) NABH4/EtOH (e) Zn-Hg/HCl(aq)
25) Circle alcohol(s), show the "strongest acid" due to "resonance-stabilized" conjugate
base.
1-propen-1-ol
cyclohexanol
phenol
1-pentanol
can be preferred to produce aldehyde by the oxidation of 2-meth=
5) The reagent(s)
pentanol?
NaOCI/TEMPO
(b) CrO3/H2SO4
(c) both PCC and Swern
(d) KMNO4.
Which one of the following reactions is Fischer-Esterification?
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