2.3 (a) A classical harmonic oscillator p? Kq? + 2 H 2m is in thermal contact with a heat bath at temperature T. Calculate the partition function for the oscillator in the canonical ensemble and show explicitly that (E) = kgT, ((E – (E))²) = kỷT² %3D |

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2.3 (a)
A classical harmonic oscillator
p?, Kq?
H
+
2m
2
is in thermal contact with a heat bath at temperature T. Calculate the
partition function for the oscillator in the canonical ensemble and
show explicitly that
• (E) = kgT, ((E – (E))²) = k¿T²
Transcribed Image Text:2.3 (a) A classical harmonic oscillator p?, Kq? H + 2m 2 is in thermal contact with a heat bath at temperature T. Calculate the partition function for the oscillator in the canonical ensemble and show explicitly that • (E) = kgT, ((E – (E))²) = k¿T²
2.6 (a), (b)
(a) Show that, if the kinetic energy of a particle with mass m, momentum p
is E = p²/2m, the single particle partition function can be written Z1 =
V/23, where 1 = /h²/2nmkgT is the thermal wavelength. The canonical
partition function for the ideal gas will then be
VN
ZN
N!23N
(b) Use Stirling's approximation to show that in the thermodynamic limit
the Helmholtz free energy of an ideal
gas
is
V
A = -NkgT |In
N23
Transcribed Image Text:2.6 (a), (b) (a) Show that, if the kinetic energy of a particle with mass m, momentum p is E = p²/2m, the single particle partition function can be written Z1 = V/23, where 1 = /h²/2nmkgT is the thermal wavelength. The canonical partition function for the ideal gas will then be VN ZN N!23N (b) Use Stirling's approximation to show that in the thermodynamic limit the Helmholtz free energy of an ideal gas is V A = -NkgT |In N23
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