2.1 Methanol is an attractive fuel source in a sustainable, green economy. The chemical energy inherent in methanol can be utilized in a multitude of reactions. Consider the following reaction for the formation of methanol: 2CH, (9) + 0,(9) – 2CH,0H(f) Use Hess' Law to calculate the enthalpy change (in kJ-mot") of this reaction, given the following known thermochemical data: H,0(?) – H,0(g) CH, (9) + H,0(g) – 3H,(g) + CO(g) 2H,0(f) – 0,(g) + 2H;(g) 2H, (g) + CO(g) - CH,OH(?) AH, = 44.00 k) - mol AH, = 206.1 k) - mol AH, = 571.6 kj - mol AH, = -128.3 k) - mol-

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2.1
Methanol is an attractive fuel source in a sustainable, green economy. The chemical energy inherent in
methanol can be utilized in a multitude of reactions. Consider the following reaction for the formation
of methanol:
2CH,(g) + 0,(9) → 2CH,OH(f)
Use Hess' Law to caleculate the enthalpy change (in kJ-mol") of this reaction, given the following
known thermochemical data:
H,0(?) – H,0(g)
CH, (9) + H,0(g) 3H,(9) + CO(9)
2H,0(e) – 0,(g) + 2H2(g)
2H, (9) + Co(g) - CH,OH(?)
AH, = 44.00 kJ mol-
AH, = 206.1 k) · mol
AH, = 571.6 k/ mol
AH, = -128.3 k) mol-
Methanol can also be combusted in the presence of oxygen in order to release its energy. 5.24 g of
methanol was placed in a bomb calorimeter (with a known heat capacity of 0.874 kJ-K"), together with
2.50 kg water. After methanol was combusted, the temperature of the water increased by 10.3 °C.
Calculate the change in internal energy of methanol (in kJ-mol")
2.2
Transcribed Image Text:2.1 Methanol is an attractive fuel source in a sustainable, green economy. The chemical energy inherent in methanol can be utilized in a multitude of reactions. Consider the following reaction for the formation of methanol: 2CH,(g) + 0,(9) → 2CH,OH(f) Use Hess' Law to caleculate the enthalpy change (in kJ-mol") of this reaction, given the following known thermochemical data: H,0(?) – H,0(g) CH, (9) + H,0(g) 3H,(9) + CO(9) 2H,0(e) – 0,(g) + 2H2(g) 2H, (9) + Co(g) - CH,OH(?) AH, = 44.00 kJ mol- AH, = 206.1 k) · mol AH, = 571.6 k/ mol AH, = -128.3 k) mol- Methanol can also be combusted in the presence of oxygen in order to release its energy. 5.24 g of methanol was placed in a bomb calorimeter (with a known heat capacity of 0.874 kJ-K"), together with 2.50 kg water. After methanol was combusted, the temperature of the water increased by 10.3 °C. Calculate the change in internal energy of methanol (in kJ-mol") 2.2
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