2.1 If the half-life time, t'2, of the initiator AIBN in an unknown solvent is 22.6 h at 60°C, calculate its dissociation rate constant, kd, in units of reciprocal seconds.
2.1 If the half-life time, t'2, of the initiator AIBN in an unknown solvent is 22.6 h at 60°C, calculate its dissociation rate constant, kd, in units of reciprocal seconds.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:2.1 If the half-life time, t'2, of the initiator AIBN in an unknown solvent is 22.6 h at 60°C,
calculate its dissociation rate constant, kd, in units of reciprocal seconds.
Expert Solution
Step 1
The rate is dependent on the concentration. The rate constant is obtained from the rate of reaction. The amount of reactant which reversibly dissociates to form products is given by the dissociation constant. The given time in hours will be converted into seconds.
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