2. The net reaction of atmospheric ozone with nitric oxide is: O3 (g) + NO(g) NO2 (g) + O2(g) and its experimentally determined rate law is: d[0,1 = k[O(g)][NO(g)] dt %3D Two pathways were proposed for this reaction: a. Mechanism 1: O3 (g) + NO (g)→0 O (g) + O3 (g) – 202 (g) fast NO3 (g) + NO (g) → 2NO2 (g) fast O (g) +NO3 (g) slow Net Reaction: Which step is the rate-determining step? What is the predicted rate law for this mechanism? Mechanism 2: O3(g) 0(g) + O2(g) fast equilibrium NO(g) + O(g) → NO2(g) slow Net reaction: Which step is the rate-determining step? What is the predicted rate law for this mechanism?

2. The net reaction of atmospheric ozone with nitric oxide is: O3 (g) + NO(g) NO2 (g) + O2(g) and its experimentally determined rate law is: d[0,1 = k[O(g)][NO(g)] dt %3D Two pathways were proposed for this reaction: a. Mechanism 1: O3 (g) + NO (g)→0 O (g) + O3 (g) – 202 (g) fast NO3 (g) + NO (g) → 2NO2 (g) fast O (g) +NO3 (g) slow Net Reaction: Which step is the rate-determining step? What is the predicted rate law for this mechanism? Mechanism 2: O3(g) 0(g) + O2(g) fast equilibrium NO(g) + O(g) → NO2(g) slow Net reaction: Which step is the rate-determining step? What is the predicted rate law for this mechanism?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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