2. For the following one-step reaction: a. Write the two bonds broken and 2 bonds formed in the boxes provided and write the AHⓇ values of the bonds broken and formed against each bond. Use the values from the table below. b. Calculate AG in kJ/mole of the reaction, assuming that AS-0 (i.c. AG-AH"). e. Indicate with arrows where the equilibrium lies in the box between the two molecules. d. Indicate if the process is spontaneous or non-spontaneous based on the AH values? e. What type of reaction is shown below (addition, substitution, elimination, or rearrangement)? CCl₂
2. For the following one-step reaction: a. Write the two bonds broken and 2 bonds formed in the boxes provided and write the AHⓇ values of the bonds broken and formed against each bond. Use the values from the table below. b. Calculate AG in kJ/mole of the reaction, assuming that AS-0 (i.c. AG-AH"). e. Indicate with arrows where the equilibrium lies in the box between the two molecules. d. Indicate if the process is spontaneous or non-spontaneous based on the AH values? e. What type of reaction is shown below (addition, substitution, elimination, or rearrangement)? CCl₂
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2. For the following one-step reaction:
a. Write the two bonds broken and 2 bonds formed in the boxes provided and write the AHⓇ
values of the bonds broken and formed against each bond. Use the values from the table
below.
b. Calculate AG in kJ/mole of the reaction, assuming that AS - 0 (i.c. AG=AH").
c. Indicate with arrows where the equilibrium lies in the box between the two molecules.
d. Indicate if the process is spontaneous or non-spontaneous based on the AHⓇ values?
What type of reaction is shown below (addition, substitution, elimination, or
rearrangement)?
e.
CCl₂
Bonds broken
est. AG
Average Bond Enthalpies
Average Bond Enthalpies (kJ/mol)
Single Bonds
C-H 413
C-C 348
C-N
293
358
C-o
C-F 485
C-a 328
C-Br 276
C-1
240
C-S
259
Si-H
Si-Si
spontaneous or
non-spontaneous?
323
226
Si-C 301
Si-O 368
Multiple Bonds
C-C 614
C=C 830
C-N 615
C=N 891
C-O
799
C=0 1072
N-H 391
N-N 163
N-O
201
N-F 272
N-C
200
N-Br 243
H-H
436
H-F
567
H-C 431
H-Br 306
H-I
299
N-N
418
N=N 941
0-H 463
0-0 146
190
O-F
0-a 203
0-1
234
S-H
S-F
S-C
S-Br
S-S
Bonds formed
339
327
253
218
266
0₂
S-0 523
S-S
418
CCl₂
495
F-F 155
C-F 253
C1-C 242
Br-F 237
Be-C 218
Be-Be 193
ITA
1-Br
1-1
208
175
151
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