2. For the following one-step reaction: a. Write the two bonds broken and 2 bonds formed in the boxes provided and write the AHⓇ values of the bonds broken and formed against each bond. Use the values from the table below. b. Calculate AG in kJ/mole of the reaction, assuming that AS-0 (i.c. AG-AH"). e. Indicate with arrows where the equilibrium lies in the box between the two molecules. d. Indicate if the process is spontaneous or non-spontaneous based on the AH values? e. What type of reaction is shown below (addition, substitution, elimination, or rearrangement)? CCl₂

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2. For the following one-step reaction:
a. Write the two bonds broken and 2 bonds formed in the boxes provided and write the AHⓇ
values of the bonds broken and formed against each bond. Use the values from the table
below.
b. Calculate AG in kJ/mole of the reaction, assuming that AS - 0 (i.c. AG=AH").
c. Indicate with arrows where the equilibrium lies in the box between the two molecules.
d. Indicate if the process is spontaneous or non-spontaneous based on the AHⓇ values?
What type of reaction is shown below (addition, substitution, elimination, or
rearrangement)?
e.
CCl₂
Bonds broken
est. AG
Average Bond Enthalpies
Average Bond Enthalpies (kJ/mol)
Single Bonds
C-H 413
C-C 348
C-N
293
358
C-o
C-F 485
C-a 328
C-Br 276
C-1
240
C-S
259
Si-H
Si-Si
spontaneous or
non-spontaneous?
323
226
Si-C 301
Si-O 368
Multiple Bonds
C-C 614
C=C 830
C-N 615
C=N 891
C-O
799
C=0 1072
N-H 391
N-N 163
N-O
201
N-F 272
N-C
200
N-Br 243
H-H
436
H-F
567
H-C 431
H-Br 306
H-I
299
N-N
418
N=N 941
0-H 463
0-0 146
190
O-F
0-a 203
0-1
234
S-H
S-F
S-C
S-Br
S-S
Bonds formed
339
327
253
218
266
0₂
S-0 523
S-S
418
CCl₂
495
F-F 155
C-F 253
C1-C 242
Br-F 237
Be-C 218
Be-Be 193
ITA
1-Br
1-1
208
175
151
Transcribed Image Text:2. For the following one-step reaction: a. Write the two bonds broken and 2 bonds formed in the boxes provided and write the AHⓇ values of the bonds broken and formed against each bond. Use the values from the table below. b. Calculate AG in kJ/mole of the reaction, assuming that AS - 0 (i.c. AG=AH"). c. Indicate with arrows where the equilibrium lies in the box between the two molecules. d. Indicate if the process is spontaneous or non-spontaneous based on the AHⓇ values? What type of reaction is shown below (addition, substitution, elimination, or rearrangement)? e. CCl₂ Bonds broken est. AG Average Bond Enthalpies Average Bond Enthalpies (kJ/mol) Single Bonds C-H 413 C-C 348 C-N 293 358 C-o C-F 485 C-a 328 C-Br 276 C-1 240 C-S 259 Si-H Si-Si spontaneous or non-spontaneous? 323 226 Si-C 301 Si-O 368 Multiple Bonds C-C 614 C=C 830 C-N 615 C=N 891 C-O 799 C=0 1072 N-H 391 N-N 163 N-O 201 N-F 272 N-C 200 N-Br 243 H-H 436 H-F 567 H-C 431 H-Br 306 H-I 299 N-N 418 N=N 941 0-H 463 0-0 146 190 O-F 0-a 203 0-1 234 S-H S-F S-C S-Br S-S Bonds formed 339 327 253 218 266 0₂ S-0 523 S-S 418 CCl₂ 495 F-F 155 C-F 253 C1-C 242 Br-F 237 Be-C 218 Be-Be 193 ITA 1-Br 1-1 208 175 151
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