2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (C,H,),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH in DMSO. (c) The solvolysis of t-butyl iodide or sec-butyl iodide in methanol. (d) The reaction of 3-bromopentane or 3-bromo-2,4-dimethylpentane with hot concentrated KOC(CH,), in HOC(CH;);.
2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (C,H,),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH in DMSO. (c) The solvolysis of t-butyl iodide or sec-butyl iodide in methanol. (d) The reaction of 3-bromopentane or 3-bromo-2,4-dimethylpentane with hot concentrated KOC(CH,), in HOC(CH;);.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Hi- we do this in class-it is not graded-need help with number 2 please.
Transcribed Image Text:NH3
(i)
CH;CH,CH,CH,Br
2.
For each of the following indicate which reaction will occur faster. Explain your
reasoning. (No credit will be given for guesses)
(a) The reaction of (C,H3),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH
(b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH in DMSO.
(c) The solvolysis of t-butyl iodide or sec-butyl iodide in methanol.
(d) The reaction of 3-bromopentane or 3-bromo-2,4-dimethylpentane with hot concentrated
КОС(СH,); in HОС(СH);,
(e) The reaction of 1-bromo-1-phenylethane or 2-bromopropane with KOH in hot ethanol.
(f) The reaction of cis-1-bromo-3-t-butylcyclohexane or trans-1-bromo-3-t-butylcyclohexane
with hot concentrated NaOCH, in methanol.
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