2. Consider the reaction schemekıA ²2Ck-1in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume thatinitially A and B are present at concentrations ao and bo respectively, and no C is present.Let a =2A=Band= [A], b = [B] and c = = [C].(a) Assuming mass action kinetics, write down a system of differential equations for da, ddescribing the reaction.dt, and dedtdt(b)Derive a conservation law governing the reaction. Show all working.

Reversible reaction: A reversible reaction is one that involves a simultaneous transformation of…

2. Consider the reaction scheme kı A k², 2C k-1 in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume that initially A and B are present at concentrations ao and bo respectively, and no C is present. Let a = [A], b = [B] and c= [C]. (a) (b) 2A B and Assuming mass action kinetics, write down a system of differential equations for de, de and de describing the reaction. dt Derive a conservation law governing the reaction. Show all working.

2. Consider the reaction scheme kı A k², 2C k-1 in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume that initially A and B are present at concentrations ao and bo respectively, and no C is present. Let a = [A], b = [B] and c= [C]. (a) (b) 2A B and Assuming mass action kinetics, write down a system of differential equations for de, de and de describing the reaction. dt Derive a conservation law governing the reaction. Show all working.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. The following data was obtained from decomposition of nitrogen oxide (NO). 2HX H2 + X2 T(K) 703 733 759 791 811 836 865 k (L mol-¹s-¹) Find; 0.011 0.035 0.105 0.343 0.790 2.14 4.95 (a) The activation energy, Ea. (b) The Arrhenius constant, A (c) The collision frequency, ZAA (d) The following mechanism was suggested for the reaction. Is the mechanism meet with the order of reaction? X₂ = X + X X + H2 H + XH + HX2 X + H₂ Fast Slow Fast