2. Consider the reaction scheme kı A k², 2C k-1 in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume that initially A and B are present at concentrations ao and bo respectively, and no C is present. Let a = [A], b = [B] and c= [C]. (a) (b) 2A B and Assuming mass action kinetics, write down a system of differential equations for de, de and de describing the reaction. dt Derive a conservation law governing the reaction. Show all working.
2. Consider the reaction scheme kı A k², 2C k-1 in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume that initially A and B are present at concentrations ao and bo respectively, and no C is present. Let a = [A], b = [B] and c= [C]. (a) (b) 2A B and Assuming mass action kinetics, write down a system of differential equations for de, de and de describing the reaction. dt Derive a conservation law governing the reaction. Show all working.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![2. Consider the reaction scheme
kı
A ²2C
k-1
in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume that
initially A and B are present at concentrations ao and bo respectively, and no C is present.
Let a =
2A=
B
and
= [A], b = [B] and c = = [C].
(a) Assuming mass action kinetics, write down a system of differential equations for da, d
describing the reaction.
dt, and de
dt
dt
(b)
Derive a conservation law governing the reaction. Show all working.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Faa545331-ae09-41a0-b370-eb1740abcd0a%2F50c7b0b3-4ced-40ac-9ddd-cf10067192d5%2Fvfiuxh_processed.png&w=3840&q=75)
Transcribed Image Text:2. Consider the reaction scheme
kı
A ²2C
k-1
in which A undergoes reversible dimerisation into B while also decaying into a product C. Assume that
initially A and B are present at concentrations ao and bo respectively, and no C is present.
Let a =
2A=
B
and
= [A], b = [B] and c = = [C].
(a) Assuming mass action kinetics, write down a system of differential equations for da, d
describing the reaction.
dt, and de
dt
dt
(b)
Derive a conservation law governing the reaction. Show all working.
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