2.Consider the molecule trans-FNNF (N;F»).(a) To which point group does it belong?(b) How many degrees of freedom does trans-N2F2possess?(c) How many fundamental vibrations are expected?(d) To which irreducible representations do the translations, rotations, and vibrations belong?(You need to work out the complete three-dimensional analyses for all 4 atoms and reducethe representation into its irreducible components using r3n = Xi N;).

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2. Consider the molecule trans-FNNF (N¿F2). (a) To which point group does it belong? (b) How many degrees of freedom does trans-N¿F2possess? (c) How many fundamental vibrations are expected?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

2.
Consider the molecule trans-FNNF (N;F»).
(a) To which point group does it belong?
(b) How many degrees of freedom does trans-N2F2possess?
(c) How many fundamental vibrations are expected?
(d) To which irreducible representations do the translations, rotations, and vibrations belong?
(You need to work out the complete three-dimensional analyses for all 4 atoms and reduce
the representation into its irreducible components using r3n = Xi N;).

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