(a) Draw a rough schematic of the series of resonances corresponding to a vibrational transition for a diatomic. Label the P and R branches, explain what the difference is between them, and indicate what the spacing is between the resonance lines. (b) What is the main information about a diatomic molecule that one can obtain from vibrational and rotational transition frequencies (assuming that the reduced mass is known)?
(a) Draw a rough schematic of the series of resonances corresponding to a vibrational transition for a diatomic. Label the P and R branches, explain what the difference is between them, and indicate what the spacing is between the resonance lines. (b) What is the main information about a diatomic molecule that one can obtain from vibrational and rotational transition frequencies (assuming that the reduced mass is known)?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:(a) Draw a rough schematic of the series of resonances corresponding to a vibrational transition
for a diatomic. Label the P and R branches, explain what the difference is between them, and
indicate what the spacing is between the resonance lines.
(b) What is the main information about a diatomic molecule that one can obtain from vibrational
and rotational transition frequencies (assuming that the reduced mass is known)?
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