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2. a. The thiocarbonate ion, SO:, where carbon is the central atom, is essential carbonate. While there are three resonance structures for this ion, only one is important. Which one and why? b. How many peaks are there in the CO stretching frequency region of the IR spectrum of thiocarbonate? Be sure to fully justify your answer here. c. Is thiocarbonate a pi donor or pi acceptor ligand? Why might the answer to this be ambiguous? d. What kind of data could you use to try and settle this ambiguity?

2. a. The thiocarbonate ion, SO:, where carbon is the central atom, is essential carbonate. While there are three resonance structures for this ion, only one is important. Which one and why? b. How many peaks are there in the CO stretching frequency region of the IR spectrum of thiocarbonate? Be sure to fully justify your answer here. c. Is thiocarbonate a pi donor or pi acceptor ligand? Why might the answer to this be ambiguous? d. What kind of data could you use to try and settle this ambiguity?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. a. The thiocarbonate ion, CSO2, where carbon is the central atom, is essentially a sulfur version of carbonate. While there are three resonance structures for this ion, only one is important. Which one and why? b. How many peaks are there in the CO stretching frequency region of the IR spectrum of thiocarbonate? Be sure to fully justify your answer here. c. Is thiocarbonate a pi donor or pi acceptor ligand? Why might the answer to this be ambiguous? d. What kind of data could you use to try and settle this ambiguity?
Transcribed Image Text:2. a. The thiocarbonate ion, CSO2, where carbon is the central atom, is essentially a sulfur version of carbonate. While there are three resonance structures for this ion, only one is important. Which one and why? b. How many peaks are there in the CO stretching frequency region of the IR spectrum of thiocarbonate? Be sure to fully justify your answer here. c. Is thiocarbonate a pi donor or pi acceptor ligand? Why might the answer to this be ambiguous? d. What kind of data could you use to try and settle this ambiguity?
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